Parahydrogen-Induced Polarization Detected with Continuous Flow Magic Angle Spinning NMR Научная публикация
| Журнал |
The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455 |
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| Вых. Данные | Год: 2013, Том: 117, Номер: 6, Страницы: 2888-2892 Страниц : 5 DOI: 10.1021/jp311345r | ||
| Ключевые слова | Atoms; Catalysts; Desorption; Magic angle spinning; Propylene | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 12-03-31298 |
Реферат:
Parahydrogen-induced polarization (PHIP) detected as an enhancement of NMR signal at pairwise addition of hydrogen atoms from the H2 molecule to olefin is an effective tool for discriminating among the possible mechanisms of hydrogenation reaction. Previously reported PHIP effects for heterogeneous hydrogenation were observed only for gas-phase molecules, that is, for those desorbed from the catalyst surface. In this case, valuable information on the possible intermediates and the reaction products on the catalyst surface could not be provided. In this paper, a magic angle spinning (MAS) NMR technique was applied for the first time for registration of PHIP produced in hydrogenation of propene with para-H2 on the Pt-supported on metal oxide catalyst (Pt/TiO2). We demonstrate that the use of the 1H MAS NMR technique under the condition of a continuous flow of the reagents (CF MAS NMR) enables registration of polarization in both the gas phase and the adsorbed species. Application of CF MAS NMR could be useful for detecting PHIP effects on heterogeneous catalysts and for the study of the mechanisms of heterogeneously catalyzed hydrogenation reactions.
Библиографическая ссылка:
Arzumanov S.S.
, Stepanov A.G.
Parahydrogen-Induced Polarization Detected with Continuous Flow Magic Angle Spinning NMR
The Journal of Physical Chemistry C. 2013. V.117. N6. P.2888-2892. DOI: 10.1021/jp311345r WOS Scopus РИНЦ CAPlusCA OpenAlex
Parahydrogen-Induced Polarization Detected with Continuous Flow Magic Angle Spinning NMR
The Journal of Physical Chemistry C. 2013. V.117. N6. P.2888-2892. DOI: 10.1021/jp311345r WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 16 нояб. 2012 г. |
| Принята к публикации: | 22 янв. 2013 г. |
| Опубликована online: | 4 февр. 2013 г. |
| Опубликована в печати: | 14 февр. 2013 г. |
Идентификаторы БД:
| Web of science: | WOS:000315181800059 |
| Scopus: | 2-s2.0-84873969798 |
| РИНЦ: | 20434361 |
| Chemical Abstracts: | 2013:126661 |
| Chemical Abstracts (print): | 158:254980 |
| OpenAlex: | W2312592571 |