Heterogeneous Selective Oxidation of Alkenes to α,β-Unsaturated Ketones over Coordination Polymer MIL-101 Full article
| Journal |
Advanced Synthesis and Catalysis
ISSN: 1615-4150 , E-ISSN: 1615-4169 |
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| Output data | Year: 2010, Volume: 352, Number: 17, Pages: 2943-2948 Pages count : 6 DOI: 10.1002/adsc.201000516 | ||||
| Tags | α,β-unsaturated ketones, allylic oxidation, heterogeneous catalysis, metal-organic frameworks, MIL-101, tert-butyl hydroperoxide | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 09-03-12112 |
| 2 | Russian Foundation for Basic Research | 09-03-93109 |
| 3 | Siberian Branch of the Russian Academy of Sciences | 107 |
Abstract:
The mesoporous metal-organic framework MIL-101 is an efficient heterogeneous catalyst for the selective allylic oxidation of alkenes with tert-butyl hydroperoxide. The selectivity towards α,β-unsaturated ketones reaches 86–93%. The temperature of the catalyst activation strongly affects the ketone yield. MIL-101 is stable to chromium leaching, behaves as a true heterogeneous catalyst, can be easily recovered by filtration, and can be reused several times without loss of the catalytic performance.
Cite:
Maksimchuk N.V.
, Kovalenko K.A.
, Fedin V.P.
, Kholdeeva O.A.
Heterogeneous Selective Oxidation of Alkenes to α,β-Unsaturated Ketones over Coordination Polymer MIL-101
Advanced Synthesis and Catalysis. 2010. V.352. N17. P.2943-2948. DOI: 10.1002/adsc.201000516 WOS Scopus РИНЦ ANCAN OpenAlex
Heterogeneous Selective Oxidation of Alkenes to α,β-Unsaturated Ketones over Coordination Polymer MIL-101
Advanced Synthesis and Catalysis. 2010. V.352. N17. P.2943-2948. DOI: 10.1002/adsc.201000516 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 1, 2010 |
| Published online: | Nov 12, 2010 |
| Published print: | Nov 22, 2010 |
Identifiers:
| Web of science: | WOS:000284620400015 |
| Scopus: | 2-s2.0-78649580629 |
| Elibrary: | 16679456 |
| Chemical Abstracts: | 2010:1440252 |
| Chemical Abstracts (print): | 154:157569 |
| OpenAlex: | W2115427755 |