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Synthesis of Pharmaceutically Relevant Terpene Amines via One-Pot Alcohol Amination over Gold Catalysts Тезисы доклада

Конференция The 8th Tokyo Conference on Advanced Catalytic Science and Technology
05-10 авг. 2018 , Токио
Сборник The 8th Tokyo Conference on Advanced Catalytic Science and Technology
Сборник, 2018.
Вых. Данные Год: 2018, Номер статьи : P3013, Страниц : 2
Ключевые слова amination, gold catalyst, biomass
Авторы Demidova Yuliya S. 1,2 , Simakova Irina L. 1,2 , Suslov Evgeny V. 3 , . Mozhajcev Evgeny S 3 , Konstantin P.Volcho 2,3 , Salakhutdinov Nariman F. 2,3 , Simakov Andrey V. 4 , Murzin Dmitry Yu. 5
Организации
1 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Novosibirsk, 630090, Russia
3 Novosibirsk Institute of Organic Chemistry, Novosibirsk, 630090, Russia
4 Universidad Nacional Autónoma de México, Centro de Nanociencias y Nanotecnología, Ensenada, 22860, México
5 Process Chemistry Centre, Åbo Akademi University, Turku/Åbo, FI-20500, Finland

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 16-33-60028

Реферат: One-pot terpene alcohols amination was studied over nanosized gold catalysts supported on metal oxides with equimolar amounts of the substrates under nitrogen pressure. The products distribution and conversion were found to depend on support nature, catalyst redox activation and active metal component composition. The reaction kinetics was modeled based on the mechanistic considerations with the catalyst deactivation step introduced into the mechanism. The effect of the substrate structure was explored. Introduction of hydrogen donors was efficient for controlled hydrogenation of C=N bond preserving C=C bond without addition of external molecular hydrogen resulting in the enhanced yield of the desired amine
Библиографическая ссылка: Demidova Y.S. , Simakova I.L. , Suslov E.V. , . Mozhajcev E.S. , K.P.V. , Salakhutdinov N.F. , Simakov A.V. , Murzin D.Y.
Synthesis of Pharmaceutically Relevant Terpene Amines via One-Pot Alcohol Amination over Gold Catalysts
В сборнике The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
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