On the Feasibility of Bifunctional Hydrogen Oxidation on Ni and NiCu Surfaces | Sciact - CRIS-system of Boreskov Institute of Catalysis

On the Feasibility of Bifunctional Hydrogen Oxidation on Ni and NiCu Surfaces Full article

Journal

Electrochimica Acta
ISSN: 0013-4686 , E-ISSN: 1873-3859

Output data

Year: 2019, Volume: 305, Pages: 452-458 Pages count : 7 DOI: 10.1016/j.electacta.2019.03.030

Tags

Hydrogen oxidation reaction, Nickel and nickel copper, Bifunctional mechanism, DFT and Monte Carlo simulations, Kinetic modeling

Authors

Salmazo D. ^1,5 , Juarez M.F. ¹ , Oshchepkov A.G. ² , Cherstiouk O.V. ² , Bonnefont A. ³ , Shermukhamedov S.A. ⁴ , Nazmutdinov R.R. ⁴ , Schmickler W. ¹ , Savinova E.R. ⁵

Affiliations

1	Institute of Theoretical Chemistry, Ulm University, D-89069, Ulm, Germany
2	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
3	Institut de Chimie de Strasbourg, UMR 7177, CNRS-University of Strasbourg, 67070, Strasbourg, France
4	Kazan National Research Technological University, 420015, Kazan, Russian Federation
5	ICPEES, UMR 7515, CNRS-University of Strasbourg, 67087, Strasbourg Cedex, France

Funding (3)

1	Russian Foundation for Basic Research	17-53-150008
2	National Scientific and Technical Research Council
3	National Council for Scientific and Technological Development	248817/2013-2

Nickel is a promising alternative to noble metal catalysts for hydrogen electrocatalysis in alkaline membrane fuel cells and electrolyzers. To boost its electrocatalytic activity, it is often associated with other metals, like Cu. In this work, we combine density functional theory (DFT), Monte Carlo calculations and kinetic modeling in order to shed light on the origin of the experimentally observed activity enhancement on bimetallic NiCu nanoparticles containing ca. 5% of Cu compared to pure Ni (Topics in Catalysis, 58, (2015), 1181–1192; J. Electroanal. Chem., 783, (2016), 146–151). It is shown that the bifunctional HOR mechanism, where H ad and OH ad recombine to form water, is not viable on the monometallic Ni electrode because of the strong hydrogen adsorption and the high activation energy barrier of the recombination reaction. On bimetallic NiCu surfaces, DFT calculations predict a significant weakening of H ad adsorption energy as well as a decrease of the activation barrier of the recombination reaction for ca. 50% Cu surface coverage. Monte Carlo simulations reveal that the surface of NiCu nanoparticles is enriched in Cu atoms even for a small (ca. 5%) Cu atomic fraction in the bulk. Kinetic modeling suggests that the experimental data for NiCu nanoparticles can be well reproduced either considering fast recombination step (bifunctional mechanism) or fast (10-fold enhancement compared to pure Ni) Volmer step (Heyrovsky-Volmer mechanism). © 2019 Elsevier Ltd

Salmazo D. , Juarez M.F. , Oshchepkov A.G. , Cherstiouk O.V. , Bonnefont A. , Shermukhamedov S.A. , Nazmutdinov R.R. , Schmickler W. , Savinova E.R.
On the Feasibility of Bifunctional Hydrogen Oxidation on Ni and NiCu Surfaces
Electrochimica Acta. 2019. V.305. P.452-458. DOI: 10.1016/j.electacta.2019.03.030 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Oct 31, 2018
Accepted:	Mar 4, 2019
Published online:	Mar 7, 2019
Published print:	May 10, 2019

Web of science:	WOS:000462774000049
Scopus:	2-s2.0-85063101730
Elibrary:	38671514
Chemical Abstracts:	2019:563757
OpenAlex:	W2921909752

DB	Citing
Scopus	31
Web of science	30
Elibrary	26
OpenAlex	33