Nickel Catalysts Based on Porous Nickel for Methane Steam Reforming | Sciact - CRIS-system of Boreskov Institute of Catalysis

Nickel Catalysts Based on Porous Nickel for Methane Steam Reforming Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2008, Volume: 49, Number: 3, Pages: 428-434 Pages count : 7 DOI: 10.1134/S0023158408030178

Tags

Nickel Oxide; Nickel Catalyst; Nickel Particle; Methane Steam; Porous Nickel

Authors

Sabirova Z.A. ¹ , Danilova M.M. ¹ , Zaikovskii V.I. ¹ , Kuzin N.A. ¹ , Kirillov V.A. ¹ , Krieger T.A. ¹ , Meshheryakov V.D. ¹ , Rudina N.A. ¹ , Brizitskii O.F. ² , Khrobostov L.N. ²

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	All-Russia Research Institute of Experimental Physics, Russian Federal Nuclear Center, Sarov, Nizhegorodskaya oblast, 607200 Russia

The influence of synthesis conditions on the phase composition and texture of porous nickel supports as plates with a magnesium oxide underlayer were investigated by X-ray diffraction, low-temperature nitrogen absorption, and electron microscopy combined with X-ray microanalysis. Nickel catalysts supported on these plates were studied. Thermal treatment of Mg(NO3)2 in nitrogen yields a magnesium oxide underlayer with a small specific surface area (support I). The replacement of nitrogen with hydrogen leads to a larger surface area (support II). The formation of MgO is accompanied by the incorporation of Ni2+ cations from the oxide film into the underlayer. Upon subsequent reduction with hydrogen or under the action of the reaction medium, these cations form fine crystallites of nickel. The supports having an oxide underlayer show a higher activity in methane steam reforming than the initial metallic nickel. Nickel catalysts on supports I and II show similar activities. The activity of the catalysts was stable throughout 50-h-long tests; no carbon deposits were detected by TEM

Sabirova Z.A. , Danilova M.M. , Zaikovskii V.I. , Kuzin N.A. , Kirillov V.A. , Krieger T.A. , Meshheryakov V.D. , Rudina N.A. , Brizitskii O.F. , Khrobostov L.N.
Nickel Catalysts Based on Porous Nickel for Methane Steam Reforming
Kinetics and Catalysis. 2008. V.49. N3. P.428-434. DOI: 10.1134/S0023158408030178 WOS Scopus РИНЦ ANCAN OpenAlex

Сабирова З.А. , Данилова М.М. , Зайковский В.И. , Кузин Н.А. , Кириллов В.А. , Кригер Т.А. , Мещеряков В.Д. , Рудина Н.А. , Бризицкий О.Ф. , Хробостов Л.Н.
Никелевые катализаторы на основе пористого никеля для реакции паровой конверсии метана
Кинетика и катализ. 2008. Т.49. №3. С.449-456. РИНЦ

Submitted:	Oct 17, 2006
Published print:	May 1, 2008
Published online:	Jun 14, 2008

Web of science:	WOS:000256778200017
Scopus:	2-s2.0-45749122336
Elibrary:	13589303
Chemical Abstracts:	2008:727147
Chemical Abstracts (print):	151:81558
OpenAlex:	W2062081647

DB	Citing
Web of science	20
Scopus	18
Elibrary	16
OpenAlex	20