Bismuth Modified Pd/C as Catalysts for Hydrogen Related Reactions Научная публикация
Журнал |
Electrochemistry Communications
ISSN: 1388-2481 |
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Вых. Данные | Год: 2010, Том: 12, Номер: 11, Страницы: 1490-1492 Страниц : 3 DOI: 10.1016/j.elecom.2010.08.014 | ||||||
Ключевые слова | Bismuth, HOR/HER, Nanoparticle, Palladium, PEMFC, Sibunit carbon | ||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | European Commission | 32175 FP6-2004-NMP-TI-4 FCANODE |
2 | Министерство образования и науки Российской Федерации | 02.740.11.5084 |
Реферат:
The electrocatalytic activity of bimetallic BiPd catalysts supported on Sibunit carbon towards hydrogen oxidation/evolution reactions (HOR/HER) was studied in a gas diffusion electrode (GDE) setup. Catalysts were synthesized by deposition of Pd on the carbon support, followed by impregnation of Pd/C precursor with Bi(NO3)3 solution and reduction in hydrogen. Transmission electron microscopy and local EDX elemental analysis revealed that BiPd/C catalysts contain bimetallic particles with narrow size distribution with maxima at 3.2–4.1 nm. X-ray diffraction evidenced that bimetallic particles are constituted by Pd–Bi solid solution. It was shown that modification of Pd/C by bismuth increases the specific activity of palladium towards HOR/HER by a factor of 3.
Библиографическая ссылка:
Paschos O.
, Simonov A.N.
, Bobrovskaya A.N.
, Hantel M.
, Rzepka M.
, Dotzauer P.
, Popov A.N.
, Simonov P.A.
, Parmon V.N.
, Stimming U.
Bismuth Modified Pd/C as Catalysts for Hydrogen Related Reactions
Electrochemistry Communications. 2010. V.12. N11. P.1490-1492. DOI: 10.1016/j.elecom.2010.08.014 WOS Scopus РИНЦ CAPlusCA OpenAlex
Bismuth Modified Pd/C as Catalysts for Hydrogen Related Reactions
Electrochemistry Communications. 2010. V.12. N11. P.1490-1492. DOI: 10.1016/j.elecom.2010.08.014 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 13 авг. 2010 г. |
Принята к публикации: | 16 авг. 2010 г. |
Опубликована online: | 22 авг. 2010 г. |
Опубликована в печати: | 1 нояб. 2010 г. |
Идентификаторы БД:
Web of science: | WOS:000284386100009 |
Scopus: | 2-s2.0-78049298177 |
РИНЦ: | 16692146 |
Chemical Abstracts: | 2010:1332330 |
Chemical Abstracts (print): | 154:246205 |
OpenAlex: | W2015841677 |