Design, Scale-up, and Operation of a Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl Alloy Wire Mesh Honeycomb Catalytic Module in Diesel Autothermal Reforming | Sciact - CRIS-система Института катализа

Design, Scale-up, and Operation of a Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl Alloy Wire Mesh Honeycomb Catalytic Module in Diesel Autothermal Reforming Научная публикация

Журнал

Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212

Вых. Данные

Год: 2019, Том: 374, Страницы: 511-519 Страниц : 9 DOI: 10.1016/j.cej.2019.05.205

Ключевые слова

Alumina; Autothermal reforming; Ceria-zirconia; Diesel; Hexadecane; Hydrogen-rich stream; Rhodium; Structured catalyst; Syngas; Wire metal mesh

Авторы

Rogozhnikov V.N. ¹ , Kuzin N.A. ² , Snytnikov P.V. ^1,2,3 , Potemkin D.I. ^1,3 , Shoynkhorova T.B. ¹ , Simonov P.A. ¹ , Shilov V.A. ^1,3 , Ruban N.V. ^1,3 , Kulikov A.V. ¹ , Sobyanin V.A. ¹

Организации

1	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
2	UNICAT Ltd, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
3	Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, Russian Federation

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0011
2	Российский научный фонд	19-19-00257

Catalytic autothermal reforming is considered as one of the most effective methods for production of hydrogen from heavy hydrocarbon fuels for solid oxide fuel cells (SOFC). Diesel is an attractive fuel because of its high energy density, widespread use and well – developed infrastructure. Catalysts supported on structured carriers (e.g. FeCrAl modules) provide controlled reaction conditions throughout the reactor volume that favorably compete, for example, with fixed bed reactors. The use of structured catalysts provides efficient heat and mass transfer, low gas dynamic resistance, and high catalyst performance that facilitates the reduction of catalyst quantity per unit volume of the reactor. The ability to perform the process under controlled optimum conditions leads to increased selectivity and minimizes undesirable side reactions, such as coke formation. In the present work, the active component Rh/Ce0.75Zr0.25O2-δ was supported on FeCrAl metal meshes using Al2O3 as a binding structural component. The obtained catalysts Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl were tested in laboratory and pilot scale reactors in n-hexadecane and diesel autothermal reaction conditions. Winter grade diesel used in the experiments contained up to 31% of aromatics. Operating conditions were found to provide a 100% conversion of n-hexadecane and diesel and stable catalyst activity for a long time-on-stream exposure. The catalysts provided equilibrium product distribution and a maximum syngas (CO + H2) productivity of 3 m3Lcat −1h−1 (STP) at the studied experimental conditions. The produced syngas can be supplied as a fuel for power generation units based on high-temperature solid oxide fuel cells. © 2019 Elsevier B.V.

Rogozhnikov V.N. , Kuzin N.A. , Snytnikov P.V. , Potemkin D.I. , Shoynkhorova T.B. , Simonov P.A. , Shilov V.A. , Ruban N.V. , Kulikov A.V. , Sobyanin V.A.
Design, Scale-up, and Operation of a Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl Alloy Wire Mesh Honeycomb Catalytic Module in Diesel Autothermal Reforming
Chemical Engineering Journal. 2019. V.374. P.511-519. DOI: 10.1016/j.cej.2019.05.205 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	29 мая 2019 г.
Опубликована в печати:	15 окт. 2019 г.

Web of science:	WOS:000477652900046
Scopus:	2-s2.0-85066400923
РИНЦ:	41646128
Chemical Abstracts:	2020:478145
Chemical Abstracts (print):	172:284302
OpenAlex:	W2947739704

БД	Цитирований
Scopus	25
Web of science	24
РИНЦ	26
OpenAlex	26