The Surface Study of the Pd-Ga/Sibunit Catalysts for Acetylene Hydrogenation | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Surface Study of the Pd-Ga/Sibunit Catalysts for Acetylene Hydrogenation Full article

Conference

International Scientific Conference on Oil and Gas Engineering
26-28 Feb 2019 , Омск

Source

Oil and Gas Engineering (OGE-2019)
Compilation, 2019. ISBN 9780735418844.

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2019, Volume: 2141, Article number : 020019, Pages count : 7 DOI: 10.1063/1.5122038

Authors

Glyzdova D.V. ¹ , Afonasenko T.N. ¹ , Domanina T.P. ¹ , Leont’eva N.N. ¹ , Tsapina A.M. ² , Saraev A.A. ² , Shlyapin D.A. ¹

Affiliations

1	Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis SB RAS, 54, Neftezavodskaya st., Omsk, 644040, Russia
2	Federal Research Center Boreskov Institute of Catalysis, 5, Ac. Lavrentieva Pr., Novosibirsk 630090, Russia

Funding (2)

1	Federal Agency for Scientific Organizations	V.46.2.5. (АААА-А17-117021450096-8)
2	Haldor Topsoe A/S

Structural, electronic and catalytic properties of Pd-Ga/Sibunit and Pd/Sibunit catalysts are studied by XRD and XPS methods. Using XRD, it was shown that the bimetallic Pd2+xGa1–x phase is formed in the model 7%Pd- 4.62%Ga/Sibunit sample after reduction in H2 at 500 °C. XPS analysis of the samples under conditions of gradual heating in H2 showed that gallium and palladium that are located on the catalyst surface are present mainly in the oxidized state and a small amount as a mixed palladium-gallium phase. However, the introduction of gallium significantly increases the dispersion of catalytic active particles, which is likely the reason for the higher catalytic activity of Pd-Ga/Sibunit in acetylene hydrogenation but lower selectivity towards ethylene compared with the monometallic sample.

Glyzdova D.V. , Afonasenko T.N. , Domanina T.P. , Leont’eva N.N. , Tsapina A.M. , Saraev A.A. , Shlyapin D.A.
The Surface Study of the Pd-Ga/Sibunit Catalysts for Acetylene Hydrogenation
In compilation Oil and Gas Engineering (OGE-2019). 2019. – ISBN 9780735418844. DOI: 10.1063/1.5122038 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type

Published print:	Aug 28, 2019
Published online:	Aug 28, 2019

Web of science:	WOS:000516716100019
Scopus:	2-s2.0-85072102751
Elibrary:	41645381
Chemical Abstracts:	2019:2098976
OpenAlex:	W2970066865
publication_identifier.sciact_ihcp_identifier_type:	2029

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