Influence of Preparation Method of Ag–CeO2 Catalysts on Their Structure and Activity in Soot Combustion Научная публикация
Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Вых. Данные | Год: 2019, Том: 60, Номер: 4, Страницы: 432-438 Страниц : 7 DOI: 10.1134/S0023158419040141 | ||||||
Ключевые слова | Ag–CeO2 catalysts; oxygen activation; soot oxidation | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский научный фонд | 18-73-10109 |
Реферат:
The exhaust gases from motor vehicles contain unburned soot particles that pollute the environment and have a detrimental effect on the human health. The solution to this problem requires the development of new highly efficient Pt- and Pd-less catalysts for the oxidation of soot in exhaust gases. In the present work, the catalysts based on the Ag–CeO2 composition were synthesized by two techniques (co-precipitation and incipient wetness impregnation) and characterized by a complex of physicochemical methods (low-temperature nitrogen adsorption, powder X-ray diffraction (XRD), high-resolution transmission electron microscopy (TEM HR) and temperature-programmed oxidation (TPO)). The catalytic properties of the catalysts were studied in the reaction of soot oxidation. It was shown that the Ag–CeO2 catalyst prepared by the coprecipitation method was the most active in soot oxidation. The increased activity of the catalyst was associated with the formation of a complex structure, representing an agglomerate of strongly interacting silver and ceria particles, which significant affect the low-temperature activation of oxygen on the catalyst surface as shown by the TPO method. © 2019, Pleiades Publishing, Ltd.
Библиографическая ссылка:
Sadlivskaya M.V.
, Mikheeva N.N.
, Zaikovskii V.I.
, Mamontov G.V.
Influence of Preparation Method of Ag–CeO2 Catalysts on Their Structure and Activity in Soot Combustion
Kinetics and Catalysis. 2019. V.60. N4. P.432-438. DOI: 10.1134/S0023158419040141 WOS Scopus РИНЦ CAPlus OpenAlex
Influence of Preparation Method of Ag–CeO2 Catalysts on Their Structure and Activity in Soot Combustion
Kinetics and Catalysis. 2019. V.60. N4. P.432-438. DOI: 10.1134/S0023158419040141 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная:
Садливская М.В.
, Михеева Н.Н.
, Зайковский В.И.
, Мамонтов Г.В.
Влияние способа получения на структуру катализаторов Ag–CeO2 и их активность в окислении сажи
Кинетика и катализ. 2019. Т.60. №4. С.464-470. DOI: 10.1134/S0453881119040178 РИНЦ OpenAlex
Влияние способа получения на структуру катализаторов Ag–CeO2 и их активность в окислении сажи
Кинетика и катализ. 2019. Т.60. №4. С.464-470. DOI: 10.1134/S0453881119040178 РИНЦ OpenAlex
Даты:
Поступила в редакцию: | 29 нояб. 2018 г. |
Принята к публикации: | 14 мар. 2019 г. |
Опубликована в печати: | 1 июл. 2019 г. |
Опубликована online: | 26 авг. 2019 г. |
Идентификаторы БД:
Web of science: | WOS:000482926500006 |
Scopus: | 2-s2.0-85071476535 |
РИНЦ: | 41641362 |
Chemical Abstracts: | 2019:1651055 |
OpenAlex: | W2970896908 |