Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins Review
| Journal |
Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 2019, Volume: 88, Number: 11, Pages: 1094–1103 Pages count : 10 DOI: 10.1070/RCR4904 | ||||
| Tags | ENANTIOSELECTIVE CIS-DIHYDROXYLATION; TRANS-DIHYDROXYLATION; HYDROGEN-PEROXIDE; NONHEME IRON; ALKENES; DIBORATION; EPOXIDATION; HYDROLYSIS; OXIDATION; CHEMO | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 16-29-10666 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0005 |
Abstract:
Asymmetric dihydroxylation of olefinic groups is an extremely important synthetic transformation which has been widely utilized to obtain optically pure pharmaceuticals and other fine chemical products. In recent years,catalyst systems for the asymmetric C=C dihydroxylations have attracted significant interest, the major research efforts being focused on designing environmentally benign catalyst systems. This mini-review summarizes recent progress in the field, surveying both novel, less toxic modifications of the classical osmium-based catalysts, and the highly efficient and enantioselective non-osmium catalyst systems.
The bibliography includes 50 references.
Cite:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins
Russian Chemical Reviews. 2019. V.88. N11. P.1094–1103. DOI: 10.1070/RCR4904 WOS Scopus РИНЦ AN OpenAlex
Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins
Russian Chemical Reviews. 2019. V.88. N11. P.1094–1103. DOI: 10.1070/RCR4904 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Jun 5, 2019 |
| Published online: | Oct 31, 2019 |
| Published print: | Nov 30, 2019 |
Identifiers:
| Web of science: | WOS:000517796400002 |
| Scopus: | 2-s2.0-85076591702 |
| Elibrary: | 43229757 |
| Chemical Abstracts: | 2020:376437 |
| OpenAlex: | W2969860927 |