Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst Научная публикация
| Журнал |
Energies
ISSN: 1996-1073 |
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| Вых. Данные | Год: 2019, Том: 12, Номер: 18, Номер статьи : 3577, Страниц : 10 DOI: 10.3390/en12183577 | ||||
| Ключевые слова | formic acid decomposition; hydrogen production; CuO-CeO2/γ-Al2O3; multifuel processor; copper catalyst; oxygenates; fuel cell | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0011 |
Реферат:
Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 °C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.
Библиографическая ссылка:
Pechenkin A.
, Badmaev S.
, Belyaev V.
, Sobyanin V.
Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst
Energies. 2019.
V.12. N18. 3577
:1-10. DOI: 10.3390/en12183577
WOS
Scopus
РИНЦ
CAPlus
OpenAlex
Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst
Energies. 2019.
V.12. N18. 3577
:1-10. DOI: 10.3390/en12183577
WOS
Scopus
РИНЦ
CAPlus
OpenAlex
Файлы:
Полный текст от издателя
Даты:
| Поступила в редакцию: | 29 авг. 2019 г. |
| Принята к публикации: | 12 сент. 2019 г. |
| Опубликована в печати: | 19 сент. 2019 г. |
| Опубликована online: | 19 сент. 2019 г. |
Идентификаторы БД:
| Web of science: | WOS:000489101200173 |
| Scopus: | 2-s2.0-85072542374 |
| РИНЦ: | 41639885 |
| Chemical Abstracts: | 2020:659274 |
| OpenAlex: | W2974719154 |