Influence of CO Oxidation Conditions on the Mn-Zr Oxide Catalyst Structure: In situ XRD and MS Study Full article
| Journal |
Materials Letters
ISSN: 0167-577X , E-ISSN: 1873-4979 |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2020, Volume: 258, Article number : 126768, Pages count : 4 DOI: 10.1016/j.matlet.2019.126768 | ||||||
| Tags | CO oxidation; Crystal structure; In situ XRD; Solid solution; Structural; Zirconia | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0002 |
| 2 | Russian Foundation for Basic Research | 19-43-543012 |
Abstract:
Mn-Zr oxide catalyst was studied by X-ray powder diffraction and mass-spectrometry under CO oxidation reaction conditions with different CO/O2 ratio. Mn-Zr catalyst consists of manganese oxides and MnyZr1–yO2–x solid solution and was found to be stable in the environment with stoichiometric ratio of CO/O2 = 2:1 and with excess of oxygen. When the catalyst is treated in the reducing environment (pure CO and CO/O2 = 4:1) the transformation of manganese oxides to MnO and reduction of manganese cations in the structure of MnyZr1–yO2–x are observed. This process is reversible and reoxidation leads to the formation of the catalyst similar to the initial. © 2019 Elsevier B.V.
Cite:
Bulavchenko O.A.
, Vinokurov Z.S.
, Afonasenko T.N.
, Tsybulya S.V.
Influence of CO Oxidation Conditions on the Mn-Zr Oxide Catalyst Structure: In situ XRD and MS Study
Materials Letters. 2020. V.258. 126768 :1-4. DOI: 10.1016/j.matlet.2019.126768 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Influence of CO Oxidation Conditions on the Mn-Zr Oxide Catalyst Structure: In situ XRD and MS Study
Materials Letters. 2020. V.258. 126768 :1-4. DOI: 10.1016/j.matlet.2019.126768 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | Sep 20, 2019 |
| Accepted: | Oct 1, 2019 |
| Published online: | Oct 3, 2019 |
| Published print: | Jan 1, 2020 |
Identifiers:
| Web of science: | WOS:000500934600029 |
| Scopus: | 2-s2.0-85073097521 |
| Elibrary: | 41684532 |
| Chemical Abstracts: | 2019:1971341 |
| OpenAlex: | W2979162331 |
| publication_identifier.sciact_ihcp_identifier_type: | 2845 |