Efficient Epoxidation of Olefins by H2O2 Catalyzed by Iron “Helmet” Phthalocyanines | Sciact - CRIS-system of Boreskov Institute of Catalysis

Efficient Epoxidation of Olefins by H2O2 Catalyzed by Iron “Helmet” Phthalocyanines Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2013, Volume: 49, Pages: 5577-5579 Pages count : 3 DOI: 10.1039/c3cc42301h

Tags

BRIDGED DIIRON PHTHALOCYANINE; RAY CRYSTAL-STRUCTURE; BICYCLIC PHTHALOCYANINE; SELECTIVE OXIDATION; VERSATILE CATALYSTS; AROMATIC OXIDATION; METAL-COMPLEXES; C -H; REACTIVITY; METHANE

Authors

Skobelev Igor Y. ^1,2 , Kudrik Evgeny V. ^1,3 , Zalomaeva Olga V. ² , Albrieux Florian ⁴ , Afanasiev Pavel ¹ , Kholdeeva Oxana A. ² , Sorokin Alexander B. ¹

Affiliations

1	Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), UMR 5256, CNRS-Universite Lyon 1, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France
2	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, 630090, Russia
3	Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistryand Technology, 7, av. F. Engels, 153000, Ivanovo, Russia
4	Universite Lyon 1, UMR 5246, Centre Commun de Spectrometrie de Masse, 43 bd du 11 Novembre 1918, 69622 Villeurbanne cedex, France

Funding (2)

1	French Embassy in Moscow
2	The French National Research Agency	ANR-08-BLAN-0183-01

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2–2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

Skobelev I.Y. , Kudrik E.V. , Zalomaeva O.V. , Albrieux F. , Afanasiev P. , Kholdeeva O.A. , Sorokin A.B.
Efficient Epoxidation of Olefins by H2O2 Catalyzed by Iron “Helmet” Phthalocyanines
Chemical Communications. 2013. V.49. P.5577-5579. DOI: 10.1039/c3cc42301h WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 29, 2013
Accepted:	Apr 29, 2013
Published online:	May 1, 2013

Web of science:	WOS:000319406300017
Scopus:	2-s2.0-84879488908
Elibrary:	20441695
Chemical Abstracts:	2013:811192
Chemical Abstracts (print):	159:42272
OpenAlex:	W2116519222

DB	Citing
Web of science	34
Scopus	36
Elibrary	33
OpenAlex	36