Direct C–H Oxidation of Aromatic Substrates in the Presence of Biomimetic Iron Complexes Review
| Source | Frontiers of Green Catalytic Selective Oxidations Monography, Springer. Singapore.2019. 295 c. ISBN 9789813297500. WOS |
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| Output data | Year: 2019, Number: Ch. 10, Pages: 253-276 Pages count : 24 DOI: 10.1007/978-981-32-9751-7_10 | ||||
| Tags | Aromatic hydrocarbons - Bioinspired catalysis - Biomimetics - Electrophilic substitution - Enzyme models - EPR spectroscopy - Hydroxylation - Homogeneous catalysis - Hydrogen peroxide - Intermediates - Iron - Oxidation - Oxoiron species - Reaction mechanism - Selectivity | ||||
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Funding (1)
| 1 | Russian Foundation for Basic Research | 18-33-20078 |
Abstract:
This chapter is dedicated to one of the most challenging areas of oxidation catalysis—direct oxidation of
aromatic C–H groups. The development of environmentally friendly catalyst systems for the direct
hydroxylation of aromatic hydrocarbons is an important task of modern catalysis. Biomimetic approach,
based on the functional modeling of enzymes by iron complexes of a relatively simple structure, is
considered as a promising approach for designing catalyst systems for direct aromatic hydroxylation,
relying on nontoxic hydrogen peroxide used as the oxidant. The mechanism of catalytic performance of
biomimetic systems is a question of primary importance; deep insight into this issue can both substantially
rationalize the development of novel practical catalyst systems for the direct oxidation of aromatic
hydrocarbons and enrich our knowledge on the mechanisms of natural metalloenzyme-mediated
oxidations. In this chapter, the state-of-the-art in this area is provided, with the mechanistic part based
mostly on the authors’ own works.
Cite:
Lyakin O.Y.
, Talsi E.P.
Direct C–H Oxidation of Aromatic Substrates in the Presence of Biomimetic Iron Complexes
Monography chapter Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.253-276. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_10 WOS OpenAlex
Direct C–H Oxidation of Aromatic Substrates in the Presence of Biomimetic Iron Complexes
Monography chapter Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.253-276. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_10 WOS OpenAlex
Dates:
| Published online: | Oct 2, 2019 |
Identifiers:
| Web of science: | WOS:000620352300011 |
| OpenAlex: | W2977988428 |