Substituent Effect on the Structure and Photophysical Properties of Phenylamino- and Pyridylamino-2,1,3-Benzothiadiazoles Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2019, Volume: 60, Number: 10, Pages: 1670-1680 Pages count : 11 DOI: 10.1134/S0022476619100135 | ||||||
| Tags | 2,1,3-benzothiadiazole; crystal structure; electronic absorption spectroscopy; noncovalent interactions; photoluminescence | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation |
Abstract:
4-Bromo-7-phenylamino-2,1,3-benzothiadiazole (1) and 4-bromo-7-(3-pyridylamino)-2,1,3-benzo thiadiazole (2) are synthesized. Their crystal structure and photophysical properties are studied in comparison with the known phenylamino- and pyridylamino-derivatives of 2,1,3-benzothiadiazole. It is found that the aryl substituent and noncovalent interactions affect the absorption band positions and emission in a solid and a solution. It is shown that under the mechanical action on polycrystalline samples of compounds 1 and 2 a hypsochromic shift of the emission band occurs, which indicates the weakening of noncovalent intermolecular interactions. © 2019, Pleiades Publishing, Ltd.
Cite:
Sukhikh T.S.
, Khisamov R.M.
, Bashirov D.A.
, Kovtunova L.M.
, Kuratieva N.V.
, Konchenko S.N.
Substituent Effect on the Structure and Photophysical Properties of Phenylamino- and Pyridylamino-2,1,3-Benzothiadiazoles
Journal of Structural Chemistry. 2019. V.60. N10. P.1670-1680. DOI: 10.1134/S0022476619100135 WOS Scopus РИНЦ AN OpenAlex
Substituent Effect on the Structure and Photophysical Properties of Phenylamino- and Pyridylamino-2,1,3-Benzothiadiazoles
Journal of Structural Chemistry. 2019. V.60. N10. P.1670-1680. DOI: 10.1134/S0022476619100135 WOS Scopus РИНЦ AN OpenAlex
Original:
Сухих Т.С.
, Хисамов Р.М.
, Баширов Д.А.
, Ковтунова Л.М.
, Куратьева Н.В.
, Конченко С.Н.
Влияние заместителя на структуру и фотофизические свойства фениламино- и пиридиламино-2,1,3-бензотиадиазолов
Журнал структурной химии. 2019. Т.60. №10. С.1736-1745. DOI: 10.26902/JSC_id48009RSCI РИНЦ OpenAlex
Влияние заместителя на структуру и фотофизические свойства фениламино- и пиридиламино-2,1,3-бензотиадиазолов
Журнал структурной химии. 2019. Т.60. №10. С.1736-1745. DOI: 10.26902/JSC_id48009RSCI РИНЦ OpenAlex
Dates:
| Submitted: | Mar 6, 2019 |
| Accepted: | Apr 25, 2019 |
| Published print: | Oct 1, 2019 |
| Published online: | Nov 5, 2019 |
Identifiers:
| Web of science: | WOS:000494481800013 |
| Scopus: | 2-s2.0-85074581708 |
| Elibrary: | 41701968 |
| Chemical Abstracts: | 2019:2102909 |
| OpenAlex: | W2982827456 |