Structure of the First Nitrosoammine Complexes of Ruthenium with a Coordinated Sulfate Ion: [Ru(NO)(NH3)4(SO4)](HSO4)·H2O and [Ru(NO)(NH3)3Cl(SO4)]·2H2O Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2011, Volume: 52, Number: 5, Pages: 946-953 Pages count : 8 DOI: 10.1134/s0022476611050167 | ||||
| Tags | Ammine complexes; Chlorine complexes; IR spectroscopy; Nitroso complexes; Ruthenium; Single crystal X-ray diffraction; Sulfate complexes; Thermogravimetry | ||||
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Abstract:
We present a thermogravimetric study of the thermolysis of trans-[Ru(NO)(NH3)4(H2O)](HSO 4)SO4 in a helium atmosphere. The intermediate product of thermolysis (at 186°C) is treated with a 2 M H2SO4 solution to obtain the first example of a sulfate ammine complex of nitrosoruthenium [Ru(NO)(NH3)4(SO4)](HSO 4)·H2O (I) with a ∼70% yield. The product of higher temperature thermolysis (220°C) is treated with acids (H 2SO4 and HCl) to obtain a triammine complex [Ru(NO)(NH3)3Cl(SO4)]·2H2O (II). The structure of the compounds is found by single crystal XRD: Pna2 1 space group, a = 10.8005(2) Å, b = 14.9032(3) Å, c = 7.7603(1) Å) (I) and P21/n space group, a = 8.9397(1) Å, b = 8.3276(1) Å, c = 13.8993(2) Å; β = 97.358(1)° (II).
Cite:
Makhinya A.N.
, Shusharina E.A.
, Baidina I.A.
, Il’in M.A.
Structure of the First Nitrosoammine Complexes of Ruthenium with a Coordinated Sulfate Ion: [Ru(NO)(NH3)4(SO4)](HSO4)·H2O and [Ru(NO)(NH3)3Cl(SO4)]·2H2O
Journal of Structural Chemistry. 2011. V.52. N5. P.946-953. DOI: 10.1134/s0022476611050167 WOS Scopus РИНЦ ANCAN OpenAlex
Structure of the First Nitrosoammine Complexes of Ruthenium with a Coordinated Sulfate Ion: [Ru(NO)(NH3)4(SO4)](HSO4)·H2O and [Ru(NO)(NH3)3Cl(SO4)]·2H2O
Journal of Structural Chemistry. 2011. V.52. N5. P.946-953. DOI: 10.1134/s0022476611050167 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Махиня А.Н.
, Шушарина Е.А.
, Байдина И.А.
, Ильин М.А.
Строение первых нитрозоамминокомплексов рутения с координированным сульфат-ионом [Ru(NO)(NH3)4(SO4)](HSO4)·H2O И [Ru(NO)(NH3)3Cl(SO4)]·2H2O
Журнал структурной химии. 2011. Т.52. №5. С.973-980. РИНЦ
Строение первых нитрозоамминокомплексов рутения с координированным сульфат-ионом [Ru(NO)(NH3)4(SO4)](HSO4)·H2O И [Ru(NO)(NH3)3Cl(SO4)]·2H2O
Журнал структурной химии. 2011. Т.52. №5. С.973-980. РИНЦ
Dates:
| Submitted: | Aug 17, 2010 |
| Published print: | Oct 1, 2011 |
| Published online: | Nov 30, 2011 |
Identifiers:
| Web of science: | WOS:000298861300016 |
| Scopus: | 2-s2.0-84856152134 |
| Elibrary: | 18034224 |
| Chemical Abstracts: | 2011:1539412 |
| Chemical Abstracts (print): | 156:45841 |
| OpenAlex: | W2411276896 |