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Recent Advances in Bioinspired Asymmetric Epoxidations with Hydrogen Peroxide Review

Source Frontiers of Green Catalytic Selective Oxidations
Monography, Springer. Singapore.2019. 295 c. ISBN 9789813297500. WOS
Output data Year: 2019, Pages: 199-222 Pages count : 24 DOI: 10.1007/978-981-32-9751-7_8
Tags Epoxidation · Enantioselective · Asymmetric catalysis · Hydrogen peroxide · Titanium · Manganese
Authors Ottenbacher Roman V. 1,2
Affiliations
1 Институт катализа им. Г.К. Борескова СО РАН
2 Novosibirsk State University

Funding (1)

1 Russian Foundation for Basic Research 17-03-00991

Abstract: Bioinspired asymmetric epoxidation of olefins with green oxidant hydrogen peroxide attracted much research interest in recent years. A variety of catalyst systems based on transition metal complexes has emerged, providing useful techniques to obtain chiral epoxides from different classes of olefins. In this chapter, we discuss the major advances in the field, with focus on ligands design, catalyst activity, enantioselectivity, and substrate scope of asymmetric epoxidations, as well as some mechanistic aspects of these reactions
Cite: Ottenbacher R.V.
Recent Advances in Bioinspired Asymmetric Epoxidations with Hydrogen Peroxide
Monography chapter Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.199-222. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_8 WOS OpenAlex
Dates:
Published online: Oct 2, 2019
Identifiers:
Web of science: WOS:000620352300009
OpenAlex: W2977763237
Citing:
DB Citing
Web of science 1
OpenAlex 1
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