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Two Mechanisms of Thermal Expansion in Perovskite SrCo0.6Fe 0.2Nb0.2O3-z Научная публикация

Журнал Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150 , E-ISSN: 1572-8943
Вых. Данные Год: 2010, Том: 100, Номер: 1, Страницы: 79-82 Страниц : 4 DOI: 10.1007/s10973-009-0008-5
Ключевые слова Oxygen membrane, Perovskite, Thermogravimetry, XRPD
Авторы Ivanov M.G. 1 , Shmakov A.N. 1,2 , Drebushchak V.A. 2,3 , Podyacheva O.Yu. 1
Организации
1 Boreskov Institute of Catalysis SB RAS
2 Novosibirsk State University
3 Institute of Geology and Mineralogy SB RAS

Информация о финансировании (1)

1 Сибирское отделение Российской академии наук 82

Реферат: Perovskite SrCo0.6Fe0.2Nb0.2O3-z attracts attention as a promising material with high oxygen conductivity. The sample was investigated by means of high-temperature X-ray powder diffraction and thermogravimetry. Phase transition was detected near 400 °C and accompanied with significant mass loss. The phase transition affects oxygen mobility, important for the synthesis of oxygen permeable membranes. The unit cell parameters are proved to change with temperature after two effects (1) reversible conventional thermal expansion and (2) irreversible contraction-expansion due to the changes in the oxygen content. In situ high-temperature X-ray diffraction experiments allowed us to separate the contributions and to measure them as a function of temperature.
Библиографическая ссылка: Ivanov M.G. , Shmakov A.N. , Drebushchak V.A. , Podyacheva O.Y.
Two Mechanisms of Thermal Expansion in Perovskite SrCo0.6Fe 0.2Nb0.2O3-z
Journal of Thermal Analysis and Calorimetry. 2010. V.100. N1. P.79-82. DOI: 10.1007/s10973-009-0008-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 4 мая 2009 г.
Принята к публикации: 7 мая 2009 г.
Опубликована online: 19 июн. 2009 г.
Опубликована в печати: 1 апр. 2010 г.
Идентификаторы БД:
Web of science: WOS:000276744500011
Scopus: 2-s2.0-77951252896
РИНЦ: 23961172
Chemical Abstracts: 2010:476640
Chemical Abstracts (print): 154:339874
OpenAlex: W1980404251
Цитирование в БД:
БД Цитирований
Web of science 15
Scopus 15
РИНЦ 20
OpenAlex 17
Альметрики: