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Carbon Dioxide Adsorption on Carbon Nanomaterials Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2010, Том: 51, Номер: 4, Страницы: 609-614 Страниц : 6 DOI: 10.1134/S0023158410040221
Ключевые слова Activate Carbon; Sorbate; Sorption Isotherm; Micropore Volume; Sorption
Авторы Gavrilov V.Yu. 1 , Zakharov R.S. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Реферат: The adsorption of CO2 on a number of activated carbons, thermal carbon black, and oxide materials at 195 K was studied using static and dynamic techniques. The landing surface areas ω(CO2) ≈ 0.19 nm2 on thermal carbon black and the absolute values of sorption for P/P 0 < 0.4 were determined. The density of adsorbed CO2 in the micropore volume was estimated at ρ(CO2) = 0.91 g/cm3. It was demonstrated that the previously found effect of a weakening of the sorption interaction of nitrogen molecules with thin-walled materials (which manifested itself in an analysis of sorption isotherms by a comparative method) was pronounced to a lesser degree for the sorption of CO2. At the same time, the presence of supermicropores in activated carbon samples resulted in overestimated values of surface areas. A dynamic method was proposed to measure the spectra of CO2 desorption at 195–260 K using a SORBI-MS system for evaluating the binding energy of sorbate molecules with the surface.
Библиографическая ссылка: Gavrilov V.Y. , Zakharov R.S.
Carbon Dioxide Adsorption on Carbon Nanomaterials
Kinetics and Catalysis. 2010. V.51. N4. P.609-614. DOI: 10.1134/S0023158410040221 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Гаврилов В.Ю. , Захаров Р.С.
Особенности адсорбции СО2 на углеродных наноматериалах
Кинетика и катализ. 2010. Т.51. №4. С.633-638. РИНЦ
Даты:
Поступила в редакцию: 26 сент. 2009 г.
Опубликована в печати: 1 авг. 2010 г.
Опубликована online: 19 авг. 2010 г.
Идентификаторы БД:
Web of science: WOS:000281105000022
Scopus: 2-s2.0-77956301649
РИНЦ: 15335077
Chemical Abstracts: 2010:1040779
Chemical Abstracts (print): 154:344965
OpenAlex: W2020268474
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 4
РИНЦ 4
OpenAlex 6
Альметрики: