Nickel Catalysts for the Hydrodeoxygenation of Biodiesel Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2010, Том: 51, Номер: 5, Страницы: 704-709 Страниц : 6 DOI: 10.1134/S0023158410050113 | ||||||||
| Ключевые слова | Unit Cell Parameter; High Resolution Transmission Electron Microscopy; Methyl Oleate; Fatty Acid Ester; Nickel Catalyst | ||||||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Министерство образования и науки Российской Федерации | 02.526.11.6007 |
| 2 | Министерство образования и науки Российской Федерации | NK-150P |
Реферат:
A number of nickel and nickel-copper catalysts for the hydrodeoxygenation of fatty acid esters (biodiesel) were studied. The CeO2 and ZrO2 oxides and the CeO2-ZrO2 binary system were used as supports. The Ni-Cu/CeO2-ZrO2 catalyst exhibited the highest activity; it allowed us to quantitatively convert biodiesel into linear alkanes under mild conditions (290–320°C, 1.0 MPa). It was found that the selectivity of the formation of the main product (heptadecane) was 70–80%. The main correlations between the nature of catalysts and their activity under conditions of the target reaction were determined using temperature-programmed reduction, X-ray diffraction analysis, and electron microscopy. It was hypothesized that the high activity of Ni-Cu/CeO2-ZrO2 in the test reaction can be explained by the presence of a Ni1 − x Cu x (x = 0.2–0.3) solid solution as a constituent of the active component of the catalyst.
Библиографическая ссылка:
Dundich V.O.
, Khromova S.A.
, Ermakov D.Y.
, Lebedev M.Y.
, Novopashina V.M.
, Sister V.G.
, Yakimchuk A.I.
, Yakovlev V.A.
Nickel Catalysts for the Hydrodeoxygenation of Biodiesel
Kinetics and Catalysis. 2010. V.51. N5. P.704-709. DOI: 10.1134/S0023158410050113 WOS Scopus РИНЦ CAPlusCA OpenAlex
Nickel Catalysts for the Hydrodeoxygenation of Biodiesel
Kinetics and Catalysis. 2010. V.51. N5. P.704-709. DOI: 10.1134/S0023158410050113 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Дундич В.О.
, Хромова С.А.
, Ермаков Д.Ю.
, Лебедев М.Ю.
, Новопашина В.М.
, Систер В.Г.
, Ямчук А.И.
, Яковлев В.А.
Исследование никелевых катализаторов реакции гидродеоксигенации биодизеля
Кинетика и катализ. 2010. Т.51. №5. С.728-734. РИНЦ
Исследование никелевых катализаторов реакции гидродеоксигенации биодизеля
Кинетика и катализ. 2010. Т.51. №5. С.728-734. РИНЦ
Даты:
| Поступила в редакцию: | 27 окт. 2009 г. |
| Опубликована в печати: | 1 окт. 2010 г. |
| Опубликована online: | 19 окт. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000283194300011 |
| Scopus: | 2-s2.0-77958473015 |
| РИНЦ: | 16679792 |
| Chemical Abstracts: | 2010:1296866 |
| Chemical Abstracts (print): | 155:71865 |
| OpenAlex: | W2016936621 |