Dimethyl Disulfide Conversion into Dimethyl Sulfide in the Presence of Sulfidized Catalysts Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
|---|---|---|---|
| Вых. Данные | Год: 2010, Том: 51, Номер: 5, Страницы: 724-730 Страниц : 7 DOI: 10.1134/S0023158410050149 | ||
| Ключевые слова | DMDS; Dimethyl Sulfide; Cobalt Catalyst; Dimethyl Disulfide; Methanethiol | ||
| Авторы |
|
||
| Организации |
|
Реферат:
The conversion of dimethyl disulfide in the presence of various supported sulfidized metal-containing catalysts at atmospheric pressure and T = 150−350°C was studied. Sulfidized transition metals supported onto aluminum oxide were more active than catalysts based on a carbon support, silicon dioxide, amorphous aluminosilicate, and zeolite ZSM-5. The most active catalyst was 10% Co/Al2O3 prepared with the use of cobalt acetate as an active component precursor and treated with a mixture of hydrogen sulfide with hydrogen at T = 400°C. From kinetic data, it follows that all of the reaction products were formed simultaneously at a temperature of <200°C, whereas a consecutive reaction scheme took place at higher temperatures. In the presence of a sulfidized alumina-cobalt catalyst, the output of dimethyl sulfide was higher than that reached with the use of other well-known catalysts.
Библиографическая ссылка:
Mashkina A.V.
, Khairulina L.N.
Dimethyl Disulfide Conversion into Dimethyl Sulfide in the Presence of Sulfidized Catalysts
Kinetics and Catalysis. 2010. V.51. N5. P.724-730. DOI: 10.1134/S0023158410050149 WOS Scopus РИНЦ CAPlusCA OpenAlex
Dimethyl Disulfide Conversion into Dimethyl Sulfide in the Presence of Sulfidized Catalysts
Kinetics and Catalysis. 2010. V.51. N5. P.724-730. DOI: 10.1134/S0023158410050149 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Машкина А.В.
, Хайрулина Л.Н.
Исследование реакции превращения диметилдисульфида в диметилсульфид в присутствии сульфидированных катализаторов
Кинетика и катализ. 2010. Т.51. №5. С.750-756. РИНЦ
Исследование реакции превращения диметилдисульфида в диметилсульфид в присутствии сульфидированных катализаторов
Кинетика и катализ. 2010. Т.51. №5. С.750-756. РИНЦ
Даты:
| Поступила в редакцию: | 8 апр. 2009 г. |
| Опубликована в печати: | 1 окт. 2010 г. |
| Опубликована online: | 19 окт. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000283194300014 |
| Scopus: | 2-s2.0-77958485894 |
| РИНЦ: | 16679795 |
| Chemical Abstracts: | 2010:1296858 |
| Chemical Abstracts (print): | 154:210394 |
| OpenAlex: | W2048812516 |