Room-Temperature Nitrophenol Reduction over Ag–CeO2 Catalysts: The Role of Catalyst Preparation Method | Sciact - CRIS-система Института катализа

Room-Temperature Nitrophenol Reduction over Ag–CeO2 Catalysts: The Role of Catalyst Preparation Method Научная публикация

Журнал

Catalysts
ISSN: 2073-4344

Вых. Данные

Год: 2020, Том: 10, Номер: 5, Номер статьи : 580, Страниц : 12 DOI: 10.3390/catal10050580

Ключевые слова

Ag; Catalysts preparation; CeO2 catalysts; Metal; Mild conditions; Nitrophenol reduction; Support interaction

Авторы

Chernykh Mariia ¹ , Mikheeva Natalia ¹ , Zaikovskii Vladimir ^2,3 , Salaev Mikhail ¹ , Liotta Leonarda F. ⁴ , Mamontov Grigory ¹

Организации

1	Laboratory of Catalytic Research, Tomsk State University, 634050 Tomsk, Russia
2	Laboratory of Structural Research Methods, Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
3	Department of Physics, Novosibirsk State University, 630090 Novosibirsk, Russia
4	Institute for the Study of Nanostructured Materials (ISMN), (Italian) National Research Council (CNR), Via Ugo La Malfa 153, 90146 Palermo, Italy

Информация о финансировании (1)

Российский научный фонд

18-73-10109

Ag–CeO2 catalysts (20 mol % Ag) were synthesized using different techniques (co-precipitation, impregnation, and impregnation of pre-reduced ceria), characterized by XRD, N2 sorption, TEM, H2-TPR methods, and probed in room-temperature p-nitrophenol reduction into p-aminophenol in aqueous solution at atmospheric pressure. The catalyst preparation method was found to determine the textural characteristics, the oxidation state and distribution of silver and, hence, the catalytic activity in the p-nitrophenol reduction. The impregnation technique was the most favorable for the formation over the ceria surface of highly dispersed silver species that are active in the p-nitrophenol reduction (the first-order rate constant k = 0.656 min−1). © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

Chernykh M. , Mikheeva N. , Zaikovskii V. , Salaev M. , Liotta L.F. , Mamontov G.
Room-Temperature Nitrophenol Reduction over Ag–CeO2 Catalysts: The Role of Catalyst Preparation Method

Catalysts. 2020. V.10. N5. 580 :1-12. DOI: 10.3390/catal10050580 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	27 апр. 2020 г.
Принята к публикации:	20 мая 2020 г.
Опубликована в печати:	21 мая 2020 г.
Опубликована online:	21 мая 2020 г.

Web of science:	WOS:000546007000008
Scopus:	2-s2.0-85085206654
РИНЦ:	43304817
Chemical Abstracts:	2020:1235604
OpenAlex:	W3028152700

БД	Цитирований
Scopus	19
Web of science	18
РИНЦ	21
OpenAlex	18