Kinetic Study of Cellulose Transformation to Glucose and 5-HMF over Solid Acid Carbon Catalyst | Sciact - CRIS-система Института катализа

Kinetic Study of Cellulose Transformation to Glucose and 5-HMF over Solid Acid Carbon Catalyst Тезисы доклада

Конференция

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 авг. 2017 , Florence

Сборник

13th European Congress on Catalysis
Сборник, 2017.

Вых. Данные

Год: 2017, Номер статьи : 2C2.1, Страниц : 2

Авторы

Gromov N.V. ^1,2,3 , Taran O.P. ^1,3 , Kolinko P.A. ^1,4 , Aymonier C. ² , Parmon V.N. ^1,4

Организации

1	Boreskov Institute of Catalysis SB RAS, 5, pr. Lavrentieva, Novosibirsk, 630090, Russian Federation
2	CNRS, Universite Bordeaux, ICMCB UPR 9048, 87, av. du Dr Schweitzer, Pessac, 33608, France
3	Novosibirsk State Technical University, 20 pr. K. Marx, Novosibirsk, 630092, Russian Federation
4	Novosibirsk State University, 2 Pirogova str., Novosibirsk, 6300900, Russian Federation

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований French National Centre for Scientific Research	GDRI BIOMASS (МНО)
2	Посольство Франции в России

The work is devoted to kinetic modeling and an elucidation of the mechanism of the catalytic action of processing cellulose to glucose and 5-hydroxymethylfurfural (5-HMF) in the hydrolysis-dehydration reaction. Cellulose depolymerization and transformation of the main process intermediates (cellobiose, glucose, fructose, mannose and 5-HMF) were experimentally studied under hydrothermal conditions in pure water in the presence of a solid sulfonated catalyst based on the carbon material Sibunit® at 180 and 200 °C using batch and flow reactors. The catalyst was developed by the sulfonation of carbon by H2SO4. The data obtained were used to suggest the kinetic scheme of the process including the main intermediates and to determine the reaction constants. Modeling of cellulose hydrolysis-dehydration on the basis of the kinetic scheme showed that the model described the experimental results obtained at a sufficient accuracy

Gromov N.V. , Taran O.P. , Kolinko P.A. , Aymonier C. , Parmon V.N.
Kinetic Study of Cellulose Transformation to Glucose and 5-HMF over Solid Acid Carbon Catalyst
В сборнике 13th European Congress on Catalysis. 2017.

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