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Recent Progress in Catalytic Oxygenation of Aromatic C–H Groups with the Environmentally Benign Oxidants H2O2 and O2 Review

Journal Applied Organometallic Chemistry
ISSN: 0268-2605 , E-ISSN: 1099-0739
Output data Year: 2020, Volume: 34, Number: 11, Article number : e5900, Pages count : 25 DOI: 10.1002/aoc.5900
Tags aromatic oxidation, C–H activation, electrophilic substitution, hydrogen peroxide, oxygen, vitamin K3
Authors Ottenbacher Roman V. 1,2 , Talsi Evgenii P. 1,2 , Bryliakov Konstantin P. 1,2
Affiliations
1 Novosibirsk State University, Faculty of Natural Sciences, Pirogova, 1, Novosibisk, 630090, Russia
2 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibisk, 630090, Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0005
2 Russian Foundation for Basic Research 18-33-20078

Abstract: Developing efficient approaches for the selective oxygenation of aromatic C–H groups has been a challenging goal, interesting from both fundamental and practical perspectives. Designing catalyst systems for the direct production of phenol from benzene holds significant practical promise; on the contrary, novel strategies for the late‐stage selective introduction of oxygen into aromatic rings of complex organic molecules could be useful for the synthesis of fine chemicals, including biologically active compounds. Another aspect of the overall picture is toughening environmental constraints, resulting in a steady increase in the number of catalyst systems relying on environmentally benign oxidants such as H2O2 and O2. Overall, today, the realm of selective catalytic aromatic C–H oxidations is developing rapidly. This review summarizes the progress made in homo‐ and heterogeneous catalyst systems of aromatic C–H oxygenations with hydrogen peroxide and molecular oxygen, achieved in the last decade.
Cite: Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Recent Progress in Catalytic Oxygenation of Aromatic C–H Groups with the Environmentally Benign Oxidants H2O2 and O2
Applied Organometallic Chemistry. 2020. V.34. N11. e5900 :1-25. DOI: 10.1002/aoc.5900 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 13, 2020
Accepted: Jun 5, 2020
Published online: Jul 9, 2020
Published print: Nov 1, 2020
Identifiers:
Web of science: WOS:000546530300001
Scopus: 2-s2.0-85087691058
Elibrary: 45438039
Chemical Abstracts: 2020:1370079
Chemical Abstracts (print): 173:597829
OpenAlex: W3040766494
Citing:
DB Citing
Scopus 27
Web of science 25
Elibrary 21
OpenAlex 26
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