Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen | Sciact - CRIS-system of Boreskov Institute of Catalysis

Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen Conference Abstracts

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Source

13th European Congress on Catalysis
Compilation, 2017.

Output data

Year: 2017, Article number : P3.126, Pages count : 2

Authors

Kovtunov Kirill ¹ , Salnikov Oleg ¹ , Burueva Dudari ¹ , Romanov Alexey ¹ , Bukhtiyarov Valerii ² , Fedorov Alexey ³ , Copéret Christophe ³ , Koptyug Igor ¹

Affiliations

1	International Tomography Center SB RAS, Novosibirsk, 630090, Russia
2	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
3	Department of Chemistry and Applied Biosciences ETH Zürich, Zürich, Switzerland

Funding (2)

1	Russian Foundation for Basic Research	16-03-00407
2	The Ministry of Education and Science of the Russian Federation	МК-4498.2016.3

Parahydrogen-induced polarization technique (PHIP) was successfully utilized for the mechanistic investigation of the hydrogen addition selectivity over different supported metal catalysts. New insights into the semihydrogenation of 1-butyne and 2-butyne on silica-supported Cu nanoparticles were obtained. Moreover, supported palladium catalysts were also investigated in the terms of catalyst active site structure influence on the pairwise hydrogen addition selectivity and was found that the differences in the mechanism of pairwise hydrogen addition to double and triple bonds over these palladium catalysts are existed.

Kovtunov K. , Salnikov O. , Burueva D. , Romanov A. , Bukhtiyarov V. , Fedorov A. , Copéret C. , Koptyug I.
Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen
In compilation 13th European Congress on Catalysis. 2017. – C.242-243.

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