Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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| Output data | Year: 2020, Volume: 60, Number: 7, Pages: 744–750 Pages count : 7 DOI: 10.1134/S096554412007004X | ||
| Tags | oil shale, synthetic oil, catalyst | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Science Foundation | 15-13-00057 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0010 |
Abstract:
The conversion of oil shale (OS) in a hydrogen medium at a pressure of 6.0 MPa and a temperature of 400°C with the subsequent refining of the resulting products in the presence of NiMo sulfide catalysts supported on materials exhibiting different acidities has been studied. It has been found that the use of the catalysts leads to a significant decrease in the content of sulfur, nitrogen, aromatic hydrocarbons, and olefins in the liquid products obtained from the shale. It has been shown that the catalytic refining of OS hydroconversion products makes the fractional composition of synthetic oil lighter and increases the H/C ratio. The use of the catalysts leads to a decrease in the synthetic oil yield owing to the formation of hydrocarbon gas and coke deposits on the catalysts; in this case, the synthetic oil yield varies in the following order: catalyst-free (25.7 wt %) > NiMo/ASA–Al2O3 (22.0 wt %) > NiMo/Al2O3 (20.7 wt %) > NiMo/USY–Al2O3 (15.8 wt %).
Cite:
Dik P.P.
, Kazakov M.O.
, Saiko A.V.
, Klimov O.V.
, Pereyma V.Y.
, Golubev I.S.
, Gerasimov E.Y.
, Selishcheva S.A.
, Sorokina T.P.
, Doronin V.P.
, Noskov A.S.
Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts
Petroleum Chemistry. 2020. V.60. N7. P.744–750. DOI: 10.1134/S096554412007004X WOS Scopus РИНЦ ANCAN OpenAlex
Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts
Petroleum Chemistry. 2020. V.60. N7. P.744–750. DOI: 10.1134/S096554412007004X WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Дик П.П.
, Казаков М.О.
, Сайко А.В.
, Климов О.В.
, Перейма В.Ю.
, Голубев И.С.
, Герасимов Е.Ю.
, Селищева С.А.
, Сорокина Т.П.
, Доронин В.П.
, Носков А.С.
Превращение продуктов гидроконверсии горючего сланца в присутствии нанесенных сульфидных NiMo-катализаторов
Нефтехимия. 2020. Т.60. №4. С.456-463. DOI: 10.31857/s0028242120040048 РИНЦ OpenAlex
Превращение продуктов гидроконверсии горючего сланца в присутствии нанесенных сульфидных NiMo-катализаторов
Нефтехимия. 2020. Т.60. №4. С.456-463. DOI: 10.31857/s0028242120040048 РИНЦ OpenAlex
Dates:
| Submitted: | Aug 27, 2018 |
| Accepted: | Mar 11, 2020 |
| Published print: | Jul 1, 2020 |
| Published online: | Jul 27, 2020 |
Identifiers:
| Web of science: | WOS:000552687100003 |
| Scopus: | 2-s2.0-85088634675 |
| Elibrary: | 45418354 |
| Chemical Abstracts: | 2020:1486692 |
| Chemical Abstracts (print): | 173:561670 |
| OpenAlex: | W3045822973 |