Chemical Vapor Deposition of Silicon Nanoparticles on the Surface of Multiwalled Carbon Nanotubes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Chemical Vapor Deposition of Silicon Nanoparticles on the Surface of Multiwalled Carbon Nanotubes Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2020, Volume: 61, Number: 4, Pages: 617–627 Pages count : 10 DOI: 10.1134/S0022476620040162

Tags

nanosilicon, multiwalled carbon nanotubes, chemical vapor deposition, fluidized bed, anodes of lithium-ion batteries

Authors

Zavorin A.V. ^1,2 , Kuznetsov V.L. ¹ , Moseenkov S.I. ¹ , Tsendsuren Tsog-Ochir ² , Volodin V.A. ^2,3 , Galkin P.S. ⁴ , Ishchenko A.V. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
4	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

ГЗ-2017-2020

Chemical vapor deposition (CVD) along with thermal decomposition of monosilane (SiH4) in a fluidized bed of multiwalled carbon nanotubes (MWCNTs) is used to prepare MWCNT-Si composites containing silicon nanoparticles deposited on the nanotube surfaces. The structure of obtained Si nanoparticles in composites based on MWCNTs with different average diameters is studied by TEM, SEM, XRD, Raman spectroscopy, and FTIR spectroscopy of diffuse reflection. The size of Si particles varies from 3 nm to 45 nm and increases together with the MWCNT diameter. The major part of precipitated silica in the nanoparticles occurs in the amorphous state with small (below 3 nm in size) inclusions of nanocrystalline silicon. Specific discharge capacity of prepared composites used as the anode material for lithium-ion batteries is estimated.

Zavorin A.V. , Kuznetsov V.L. , Moseenkov S.I. , Tsendsuren T-O. , Volodin V.A. , Galkin P.S. , Ishchenko A.V.
Chemical Vapor Deposition of Silicon Nanoparticles on the Surface of Multiwalled Carbon Nanotubes
Journal of Structural Chemistry. 2020. V.61. N4. P.617–627. DOI: 10.1134/S0022476620040162 WOS Scopus РИНЦ ANCAN OpenAlex

Заворин А.В. , Кузнецов В.Л. , Мосеенков С.И. , Цог-Очир Ц. , Володин В.А. , Галкин П.С. , Ищенко А.В.
Газофазное химическое осаждение наноразмерных частиц кремния на поверхности многослойных углеродных нанотрубок
Журнал структурной химии. 2020. Т.61. №4. С.648-658. DOI: 10.26902/jsc_id54033 РИНЦ OpenAlex

Submitted:	Sep 19, 2019
Accepted:	Nov 21, 2019
Published print:	Apr 1, 2020
Published online:	Jul 29, 2020

Web of science:	WOS:000554783300016
Scopus:	2-s2.0-85088663077
Elibrary:	45428690
Chemical Abstracts:	2020:1483722
Chemical Abstracts (print):	173:520915
OpenAlex:	W3045576739

DB	Citing
Scopus	6
Web of science	5
Elibrary	5
OpenAlex	7