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Activated Carbons as Methanol Adsorbents for a New Cycle “Heat from Cold” Научная публикация

Журнал Fibers
ISSN: 2079-6439
Вых. Данные Год: 2020, Том: 8, Номер: 8, Номер статьи : 51, Страниц : 14 DOI: 10.3390/fib8080051
Ключевые слова adsorptive heating; methanol; activated carbons; useful heat; adsorption dynamics
Авторы Girnik Ilya 1 , Grekova Alexandra 1 , Gordeeva Larisa 1 , Aristov Yuri 1
Организации
1 Boreskov Institute of Catalysis

Информация о финансировании (1)

1 Российский научный фонд 16-19-10259

Реферат: Activated carbons are widely used for sustainable technology of adsorptive transformation and storage of heat. Here, we analyze the applicability of twelve commercial carbons and an innovative carbonaceous composite “LiCl confined to multi-wall carbon nanotubes” (LiCl/MWCNT) for a new cycle “Heat from Cold” (HeCol). It has recently been proposed for amplification of low- temperature ambient heat in cold countries. The analysis is made in terms of the methanol mass exchanged and the useful heat generated per cycle; the latter is the main performance indicator of HeCol cycles. The maximum specific useful heat, reaching 990 and 1750 J/g, can be obtained by using carbon Maxsorb III and the composite, respectively. For these materials, methanol adsorption dynamics under typical HeCol conditions are experimentally studied by the large pressure jump method. Before making this analysis, the fine carbon powder is consolidated by either using a binder or just pressing to obtain larger particles (ca. 2 mm). The methanol desorption from the consolidated samples of Maxsorb III at T = 2 °C is faster than for LiCl/MWCNT, and the maximum (initial) useful power reaches (2.5–4.0) kW/kg sorbent. It is very promising for designing compact HeCol units utilizing the carbon Maxsorb III.
Библиографическая ссылка: Girnik I. , Grekova A. , Gordeeva L. , Aristov Y.
Activated Carbons as Methanol Adsorbents for a New Cycle “Heat from Cold”
Fibers. 2020. V.8. N8. 51 :1-14. DOI: 10.3390/fib8080051 WOS Scopus РИНЦ CAPlus OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 26 июн. 2020 г.
Принята к публикации: 6 авг. 2020 г.
Опубликована в печати: 8 авг. 2020 г.
Опубликована online: 8 авг. 2020 г.
Идентификаторы БД:
Web of science: WOS:000567673200001
Scopus: 2-s2.0-85090152422
РИНЦ: 45385180
Chemical Abstracts: 2020:2548904
OpenAlex: W3048056886
Цитирование в БД:
БД Цитирований
Scopus 2
Web of science 2
РИНЦ 2
OpenAlex 2
Альметрики: