Abstract: Gold nanoparticles supported on TiO2 are known to catalyze vapor-phase epoxidation of propylene with molecular oxygen in the presence of H2 as the necessary reducing co reagent. Here, we report that carbon monoxide can be employed instead of hydrogen to accomplish similar reaction. The reaction of propylene, CO and O2 can be carried out in a flow reactor over Au/TiO2 at a temperature of 40–90 °C. The propylene oxide selectivity attains 80–97% at propylene conversion of 1.7–3.7%. The propylene oxide yield goes through the maximum as a function of reaction time, the maximal value being twice higher compared to yield of propylene oxide achieved by “traditional” reaction with H2/O2 mixture. Utilization efficiency of CO reaches 25%, which is comparable to that of H2 in the analogous reaction of propylene, H2 and O2. Proposed mechanism for the reaction involves the formation of specific oxygen species arising from O2 on catalytic sites reduced with CO. This is in line with generation of highly reactive oxygen species (detectable by oxygen isotopic exchange) on Au/TiO2 surface treated preliminarily with CO.

Cite: Sobolev V.I. , Koltunov K.Y.
Catalytic Epoxidation of Propylene with CO/O2 over Au/TiO2
Applied Catalysis A: General. 2014. V.476. P.197-203. DOI: 10.1016/j.apcata.2014.02.036 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Sep 2, 2013
Accepted:	Feb 27, 2014
Published online:	Mar 6, 2014
Published print:	Apr 22, 2014

Identifiers:

Web of science:	WOS:000336005600024
Scopus:	2-s2.0-84896471905
Elibrary:	21867597
Chemical Abstracts:	2014:602116
Chemical Abstracts (print):	160:559441
OpenAlex:	W2036425927

Citing:

DB	Citing
Web of science	17
Scopus	19
Elibrary	17
OpenAlex	18

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