Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts Full article

Journal

Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041

Output data

Year: 2013, Volume: 32, Number: 7, Pages: 2187-2191 Pages count : 5 DOI: 10.1021/om400061p

Tags

ETHYLENE POLYMERIZATION; OLEFIN POLYMERIZATION; VINYL POLYMERIZATION; ELECTRONIC-STRUCTURE; COBALT CATALYSTS; ACTIVE-SITES; IRON; COMPLEXES; NORBORNENE; LIGANDS

Authors

Antonov Artem A. ¹ , Samsonenko Denis G. ^2,3 , Talsi Evgenii P. ^1,3 , Bryliakov Konstantin P. ^1,3

Affiliations

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2	Nikolaev Institute of Inorganic Chemistry, Pr. Lavrentieva 3, Novosibirsk 630090, Russian Federation
3	Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090, Russian Federation

Funding (1)

Russian Foundation for Basic Research

12-03-91159

The activation of bis(imino)pyridine nickel(II) dichloride complexes [LNiCl2] with methylalumoxane (MAO) and AlMe3/[CPh3][B(C6F5)4] was studied by multinuclear NMR spectroscopy. Formation of similar outer-sphere ion pairs of the types [LNiMe]+[MeMAO]− and [LNiMe]+[B(C6F5)4]−, capable of promoting norbornene polymerization, was observed.

Antonov A.A. , Samsonenko D.G. , Talsi E.P. , Bryliakov K.P.
Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts
Organometallics. 2013. V.32. N7. P.2187-2191. DOI: 10.1021/om400061p WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jan 23, 2013
Published online:	Mar 21, 2013
Published print:	Apr 8, 2013

Web of science:	WOS:000317370000019
Scopus:	2-s2.0-84875978604
Elibrary:	20430881
Chemical Abstracts:	2013:436028
Chemical Abstracts (print):	158:447087
OpenAlex:	W2330397011

DB	Citing
Web of science	22
Scopus	23
Elibrary	23
OpenAlex	24