Multilayer Adsorption of Methanol on Platinum at Low Temperatures Full article
| Journal |
Applied Surface Science
ISSN: 0169-4332 |
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| Output data | Year: 2021, Volume: 535, Article number : 147717, Pages count : 6 DOI: 10.1016/j.apsusc.2020.147717 | ||
| Tags | Adsorption; Condensed methanol; Platinum; Structure ordering; Vibrational spectroscopy | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 075-15-2019-1876 |
Abstract:
Multilayer adsorption of methanol on the Pt(1 1 1) surface has been studied in the temperature range between 80 and 120 K by temperature-programmed desorption and polarization-modulation infrared reflection absorption spectroscopy. It has been found that the adsorption at 80–90 K leads to the formation of an amorphous layer of condensed methanol. This layer is thermally unstable, and heating to 100 K leads to the ordering of its structure via the formation of long (CH3OH)n chains, which are typical of the α phase of solid methanol. At 100 K, the adsorption of methanol directly leads to the formation of a well crystallized condensed phase. © 2020 Elsevier B.V.
Cite:
Selivanova A.V.
, Kremneva A.M.
, Saraev A.A.
, Kaichev V.V.
, Bukhtiyarov V.I.
Multilayer Adsorption of Methanol on Platinum at Low Temperatures
Applied Surface Science. 2021. V.535. 147717 :1-6. DOI: 10.1016/j.apsusc.2020.147717 WOS Scopus РИНЦ AN OpenAlex
Multilayer Adsorption of Methanol on Platinum at Low Temperatures
Applied Surface Science. 2021. V.535. 147717 :1-6. DOI: 10.1016/j.apsusc.2020.147717 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Aug 3, 2020 |
| Accepted: | Aug 27, 2020 |
| Published online: | Sep 1, 2020 |
| Published print: | Jan 1, 2021 |
Identifiers:
| Web of science: | WOS:000582373900059 |
| Scopus: | 2-s2.0-85090335455 |
| Elibrary: | 45316626 |
| Chemical Abstracts: | 2020:1806184 |
| OpenAlex: | W3082759292 |