Comparative Analysis of Physicochemical Properties of Rutile TiO2 with Hierarchical 3D Architecture Prepared by Liquid Hydrolysis of TiCl4 and Hydrothermal Method | Sciact - CRIS-system of Boreskov Institute of Catalysis

Comparative Analysis of Physicochemical Properties of Rutile TiO2 with Hierarchical 3D Architecture Prepared by Liquid Hydrolysis of TiCl4 and Hydrothermal Method Full article

Journal

Eurasian Chemico-Technological Journal
ISSN: 1562-3920

Output data

Year: 2020, Volume: 22, Number: 3, Pages: 165-175 Pages count : 11 DOI: 10.18321/ectj976

Tags

Nanostructured rutile; Porous structure; Thermal treatment; Titanium dioxide

Authors

Shikina N.V. ¹ , Yashnik S.A. ¹ , Toktarev A.V. ¹ , Ishchenko A.V. ¹ , Ushakov V.A. ¹ , Mel’gunov M.S. ¹ , Mansurov Z.A. ³ , Ismagilov Z.R. ^1,2

Affiliations

1	Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
2	Federal Research Center of Coal and Coal Chemistry Institute of Coal Chemistry and Materials Science SB RAS, 18 Sovetskiy pr., Kemerovo, Russia
3	Institute of Combustion Problems, 172 Bogenbay Batyr str., Almaty, Kazakhstan

Funding (1)

Federal Agency for Scientific Organizations

0303-2016-0004

TiO2 (rutile) samples with a hierarchical 3D nanostructure of the particles were synthesized by two methods: liquid hydrolysis of TiCl4 at 90 °С and atmospheric pressure; hydrothermal synthesis from TiCl4 at 160 °С and different [H2O]/[Ti] ratios. The effect exerted by conditions of the synthesis and post-treatments on the crystallite size, morphology, electronic properties and pore structure of the rutile samples was investigated. It was shown that severe hydrothermal conditions with the ratio [H2O]/[Ti] = 20 provide the formation of a more perfect crystal structure of rutile with a smaller band gap energy (3.00 eV against 3.06 eV for the rutile obtained by liquid hydrolysis at atmospheric pressure). The study revealed the stabilizing effect of cerium cations on the pore structure of rutile, which changes upon thermal treatment.

Shikina N.V. , Yashnik S.A. , Toktarev A.V. , Ishchenko A.V. , Ushakov V.A. , Mel’gunov M.S. , Mansurov Z.A. , Ismagilov Z.R.
Comparative Analysis of Physicochemical Properties of Rutile TiO2 with Hierarchical 3D Architecture Prepared by Liquid Hydrolysis of TiCl4 and Hydrothermal Method

Eurasian Chemico-Technological Journal. 2020. V.22. N3. P.165-175. DOI: 10.18321/ectj976 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Feb 5, 2020
Accepted:	Apr 25, 2020
Published online:	Sep 30, 2020
Published print:	Oct 1, 2020

Web of science:	WOS:000582259700003
Scopus:	2-s2.0-85094167526
Elibrary:	45192335
Chemical Abstracts:	2021:149249
OpenAlex:	W3094369383

Пока нет цитирований