The Cycle Destruction during Complex Formation of 4-salicylideneamino-3-hydrazino-5-mercapto-1,2,4-triazole with Ni (II) Ions | Sciact - CRIS-система Института катализа

The Cycle Destruction during Complex Formation of 4-salicylideneamino-3-hydrazino-5-mercapto-1,2,4-triazole with Ni (II) Ions Научная публикация

Журнал

Journal of the Chemical Society of Pakistan
ISSN: 0253-5106

Вых. Данные

Год: 2020, Том: 42, Номер: 05, Страницы: 762-766 Страниц : 5

Ключевые слова

Schiff base; Nickel complex; Thiosemicarbazone ligand; Hydrogen bonds

Авторы

Fatullayeva Perizad.A. ¹ , Medjidov Ajdar A. ¹ , Mamedov Idayat.M. ¹ , Dorovatovskiy Pavel V. ² , Zubavichus Jan.V. ³ , Khrustalev Victor.N. ⁴ , Ismayilov Rayyat Huseyn ⁵

Организации

1	Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan
2	National Research Center “Kurchatov Institute”
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
4	Peoples' Friendship University of Russia
5	“OilGasScientificResearchProject” Institute, SOCAR

Информация о финансировании (2)

1	Министерство образования и науки Российской Федерации
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2019-0003

Using single crystal X-ray diffraction method, it was shown that the interaction of 4-salicylideneamino-3-hydrazino-5-mercapto-1,2,4-triazole with Ni (II) acetate yields a complex of nickel with salicylidene-thiosemicarbazone instead of the expected complex with the corresponding Schiff base. A possible mechanism of hydrolysis of the thiotriazole ring is proposed. The N- (salicylidene) thiosemicarbazone is a tridentate and almost flat structure ligand coordinates to the nickel (II) cation through thiosemicarbazone sulphur, phenolic oxygen, and azomethine nitrogen atoms. The nickel (II) ion in the complex is four-coordinated in distorted square-planar geometry. The intermolecular hydrogen bonds N─H∙∙∙N, as well as hydrogen bonds N─H∙∙∙O, O─H∙∙∙O and O─H∙∙∙S through the solvate water molecules, give rise to the 3-D network of the complex [Ni(TSC)((NH2)2CS)]•H2O

Fatullayeva P.A. , Medjidov A.A. , Mamedov I.M. , Dorovatovskiy P.V. , Zubavichus J.V. , Khrustalev V.N. , Ismayilov R.H.
The Cycle Destruction during Complex Formation of 4-salicylideneamino-3-hydrazino-5-mercapto-1,2,4-triazole with Ni (II) Ions
Journal of the Chemical Society of Pakistan. 2020. V.42. N05. P.762-766. WOS Scopus РИНЦ

Поступила в редакцию:	16 сент. 2019 г.
Принята к публикации:	17 февр. 2020 г.
Опубликована в печати:	14 окт. 2020 г.

Web of science:	WOS:000581120200013
Scopus:	2-s2.0-85100909454
РИНЦ:	46743876

БД	Цитирований
Scopus	Нет цитирований
РИНЦ	Нет цитирований