Structure and Noncovalent Interactions of Molybdenum Disulfide Monolayers in the Layered Organo-inorganic Compound with Tetramethylguanidine Full article
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Output data | Year: 2020, Volume: 46, Number: 11, Pages: 779-785 Pages count : 7 DOI: 10.1134/s1070328420090067 | ||||||
| Tags | molybdenum disulfide, organo-inorganic compounds, structure, noncovalent interactions, hydrogen bonds | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 20-13-00241 (АААА-А20-120071090085-3) |
Abstract:
A layered compound with regularly alternating monolayers of MoS2 and N,N,N',N'-tetramethylguanidine (TMG) is synthesized by the reaction of monolayer dispersions of molybdenum disulfide containing anionic particles (MoS2)x– with protonated TMG molecules. It is found by a combination of methods (X‑ray diffraction analysis adapted for turbostrate-disordered systems, high-resolution transmission electron microscopy, FT-IR spectroscopy, and quantum-chemical calculations by the density functional theory) that the structure of MoS2 layers with octahedrally coordinated molybdenum atoms forming chains of Mo–Mo bonds is stabilized in the compound. Noncovalent binding interactions occur between the MoS2 monolayers and TMG molecules including CH…S, NH…S, and N…S contacts with the predominant contribution of contacts of the first type to the binding energy (СIF file CCDC no. 1 990439). © 2020, Pleiades Publishing, Ltd.
Cite:
Ushakov I.E.
, Goloveshkin A.S.
, Lenenko N.D.
, Takazova R.U.
, Ezernitskaya M.G.
, Korlyukov A.A.
, Zaikovskii V.I.
, Golub’ A.S.
Structure and Noncovalent Interactions of Molybdenum Disulfide Monolayers in the Layered Organo-inorganic Compound with Tetramethylguanidine
Russian Journal of Coordination Chemistry. 2020. V.46. N11. P.779-785. DOI: 10.1134/s1070328420090067 WOS Scopus РИНЦ AN OpenAlex
Structure and Noncovalent Interactions of Molybdenum Disulfide Monolayers in the Layered Organo-inorganic Compound with Tetramethylguanidine
Russian Journal of Coordination Chemistry. 2020. V.46. N11. P.779-785. DOI: 10.1134/s1070328420090067 WOS Scopus РИНЦ AN OpenAlex
Original:
Ушаков И.Е.
, Головешкин А.С.
, Лененко Н.Д.
, Таказова Р.У.
, Езерницкая М.Г.
, Корлюков А.А.
, Зайковский В.И.
, Голубь А.С.
Строение и нековалентные взаимодействия монослоев дисульфида молибдена в слоистом органо-неорганическом соединении с тетраметилгуанидином
Координационная химия. 2020. Т.46. №11. С.706-712. DOI: 10.31857/S0132344X20090066 РИНЦ OpenAlex
Строение и нековалентные взаимодействия монослоев дисульфида молибдена в слоистом органо-неорганическом соединении с тетраметилгуанидином
Координационная химия. 2020. Т.46. №11. С.706-712. DOI: 10.31857/S0132344X20090066 РИНЦ OpenAlex
Dates:
| Submitted: | Mar 14, 2020 |
| Accepted: | Apr 8, 2020 |
| Published print: | Nov 1, 2020 |
| Published online: | Nov 17, 2020 |
Identifiers:
| Web of science: | WOS:000590210600007 |
| Scopus: | 2-s2.0-85096095413 |
| Elibrary: | 45148102 |
| Chemical Abstracts: | 2020:2358612 |
| OpenAlex: | W3087116072 |