Analysis of the Deactivation of Claus Alumina Catalyst During Its Industrial Exploitation Full article
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Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2011, Volume: 3, Number: 2, Pages: 183-188 Pages count : 6 DOI: 10.1134/S2070050411020061 | ||||||
| Tags | Alumina catalyst, Deactivation, H2S oxidation, Hydrolysis of COS | ||||||
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Abstract:
Change in the activity of AO-NKZ-2 (AO-MK-2) alumina catalyst in the Claus reaction and transformations of carbonyl sulfide during operation over four years in the Claus reactor at the Magnitogorsk Metallurgical Combine’s coke-oven gas purification shop were studied at an average temperature of 245–260°C and a volume velocity of ∼2000 h−1. The rate constants of the Claus reactions and COS transformation were determined, and the changes in the active surface area of the catalyst were investigated. Fundamental discrepancies in the rate and deactivation mechanism of the Claus catalysts were revealed with respect to the reactions of the conversion of hydrogen sulfide and carbonyl sulfide.
Cite:
Kalinkin P.N.
, Kovalenko O.N.
, Platonov O.I.
Analysis of the Deactivation of Claus Alumina Catalyst During Its Industrial Exploitation
Catalysis in Industry. 2011. V.3. N2. P.183-188. DOI: 10.1134/S2070050411020061 WOS Scopus РИНЦ OpenAlex
Analysis of the Deactivation of Claus Alumina Catalyst During Its Industrial Exploitation
Catalysis in Industry. 2011. V.3. N2. P.183-188. DOI: 10.1134/S2070050411020061 WOS Scopus РИНЦ OpenAlex
Original:
Калинкин П.Н.
, Коваленко О.Н.
, Платонов О.И.
Анализ дезактивации алюмооксидного катализатора Клауса в процессе промышленной эксплуатации
Катализ в промышленности. 2011. №1. С.67-73. RSCI РИНЦ ANCAN
Анализ дезактивации алюмооксидного катализатора Клауса в процессе промышленной эксплуатации
Катализ в промышленности. 2011. №1. С.67-73. RSCI РИНЦ ANCAN
Dates:
| Submitted: | Nov 3, 2010 |
| Published print: | Jun 1, 2011 |
| Published online: | Jul 19, 2011 |
Identifiers:
| Web of science: | WOS:000433659100013 |
| Scopus: | 2-s2.0-80755125498 |
| Elibrary: | 18012620 |
| OpenAlex: | W1991131506 |