Zinc(II) and Cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) Diaminodipropyliminates: Syntheses, Structures, and Photoluminescence Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Zinc(II) and Cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) Diaminodipropyliminates: Syntheses, Structures, and Photoluminescence Properties Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2016, Volume: 42, Number: 11, Pages: 701-710 Pages count : 10 DOI: 10.1134/s1070328416110075

Tags

tetradentate Schiff bases, zinc(II) and cadmium(II) complexes, X-ray diffraction analysis, photoluminescence

Authors

Lysakova T.P. ¹ , Burlov A.S. ² , Vlasenko V.G. ² , Koshchienko Yu.V. ¹ , Aleksandrov G.G. ³ , Levchenkov S.I. ⁴ , Zubavichus Ya.V. ⁵ , Cheprasov A.S. ⁴ , Garnovskii D.A. ⁴ , Metelitsa A.V. ¹

Affiliations

1	Research Institute of Physical and Organic Chemistry, Southern Federal University
2	Research Institute of Physics, Southern Federal University
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
4	Southern Scientific Center, Russian Academy of Sciences
5	National Research Center “Kurchatov Institute”,

Chemical and electrochemical syntheses of the zinc(II) and cadmium(II) complexes with the tetradentate Schiff base (H2L), the condensation product of 2-N-tosylaminobenzaldehyde with diaminodipropylamine, are carried out. The structures, compositions, and properties of the synthesized metal complexes are studied by elemental analyses, IR spectroscopy, 1H NMR, UV spectroscopy, X-ray absorption spectroscopy, and quantum-chemical calculations. The structure of the cadmium(II) complex is determined by X-ray diffraction analysis (CIF file CCDC no. 1446393). The cadmium(II) and zinc(II) complexes exhibit luminescence in a CH2Cl2 solution in the blue spectral range (λPL = 425–428 nm) with the photoluminescence quantum yields ϕ = 0.20 and 0.75, respectively.

Lysakova T.P. , Burlov A.S. , Vlasenko V.G. , Koshchienko Y.V. , Aleksandrov G.G. , Levchenkov S.I. , Zubavichus Y.V. , Cheprasov A.S. , Garnovskii D.A. , Metelitsa A.V.
Zinc(II) and Cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) Diaminodipropyliminates: Syntheses, Structures, and Photoluminescence Properties
Russian Journal of Coordination Chemistry. 2016. V.42. N11. P.701-710. DOI: 10.1134/s1070328416110075 WOS Scopus РИНЦ ANCAN OpenAlex

Лысакова Т.П. , Бурлов А.С. , Власенко В.Г. , Кощиенко Ю.В. , Александров Г.Г. , Левченков С.И. , Зубавичус Я.В. , Чепрасов А.С. , Гарновский Д.А. , Метелица А.В.
Синтез, строение и фотолюминесцентные свойства N,N-бис(2-N-тозиламинобензилиден)диамино-дипропилиминатов цинка(II) и кадмия(II)
Координационная химия. 2016. Т.42. №11. С.665-674. DOI: 10.7868/S0132344X16110086 РИНЦ OpenAlex

Submitted:	Jan 11, 2016
Published print:	Nov 1, 2016
Published online:	Nov 4, 2016

Web of science:	WOS:000387488700002
Scopus:	2-s2.0-84994234348
Elibrary:	27589699
Chemical Abstracts:	2016:1779737
Chemical Abstracts (print):	172:314780
OpenAlex:	W2548882859

DB	Citing
Web of science	7
Scopus	5
OpenAlex	8