Bi-Reforming of Methane: Thermodynamic Equilibrium Analysis and Selection of Preferable Reaction Conditions | Sciact - CRIS-система Института катализа

Bi-Reforming of Methane: Thermodynamic Equilibrium Analysis and Selection of Preferable Reaction Conditions Научная публикация

Конференция

IX Международный Российско-Казахстанский симпозиум «Углехимия и экология Кузбасса»
12-13 окт. 2020 , Кемерово

Журнал

Journal of Physics: Conference Series
ISSN: 1742-6588 , E-ISSN: 1742-6596

Вых. Данные

Год: 2021, Том: 1749, Номер: 1, Номер статьи : 012023, Страниц : 6 DOI: 10.1088/1742-6596/1749/1/012023

Ключевые слова

Atmospheric pressure; Carbon dioxide; Coal; Ecology; Methane; Molar ratio; Thermoanalysis; Thermodynamics

Авторы

Matus E.V. ¹ , Sukhova O.B. ¹ , Ismagilov I.Z. ¹ , Kerzhentsev M.A. ¹ , Li Lei ² , Ismagilov Z.R. ^1,3

Организации

1	Federal Research Center Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science, 5 Lavrentiev Ave., 630090, Novosibirsk, Russia
2	Institute of Coal Chemistry, Chinese Academy of Sciences, 27th South Taoyuan Road, 030001, Taiyuan Shanxi, P. R. China
3	Federal Research Center of Coal and Coal Chemistry, Siberian Branch of Russian Academy of Science, 18 Sovetskiy Ave., 650000, Kemerovo, Russia

Информация о финансировании (1)

Российский фонд фундаментальных исследований

20-53-53018

To determine the optimal reaction conditions of bi-reforming of methane thermodynamic analysis of reaction was performed. The effects of process variables, such as temperature (T = 500–1000°C), pressure (P = 1–30 atm), and feed composition CH4/CO2/H2O on the product distribution were studied. It was shown that to maximize the conversion of reagents and yield of target products the high reaction temperatures (T > 800°C) and atmospheric pressure should be applied. The reaction pathway of the bi-reforming of methane is affected by the feed composition. At 800°C the molar ratio of O/C ≥ 1.1 are preferable to work at region free of carbon formation. The CO2 conversion and H2/CO ratio are controlled by the value of CO2/H2O ratio. Depending on the field of application of synthesis gas, this ratio can be tuned from 1.2 to 2.8 through variation of CO2/H2O ratio from 3 to 0.1. The selected reaction conditions (T = 800°C, P = 1 atm, CH4/CO2/H2O = 1/0.8/0.4) were applied for bi-reforming reaction over Ni catalyst which provided the process parameters close to thermodynamic equilibrium results

Matus E.V. , Sukhova O.B. , Ismagilov I.Z. , Kerzhentsev M.A. , Li L. , Ismagilov Z.R.
Bi-Reforming of Methane: Thermodynamic Equilibrium Analysis and Selection of Preferable Reaction Conditions

Journal of Physics: Conference Series. 2021. V.1749. N1. 012023 :1-6. DOI: 10.1088/1742-6596/1749/1/012023 Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	17 дек. 2020 г.
Опубликована в печати:	1 янв. 2021 г.
Опубликована online:	25 янв. 2021 г.

Scopus:	2-s2.0-85101777386
РИНЦ:	44909310
Chemical Abstracts:	2021:542475
OpenAlex:	W3126610493

БД	Цитирований
Scopus	18
РИНЦ	15
OpenAlex	16