Hydrolysis of Cellulose in the Presence of Catalysts Based on Cesium Salts of Heteropoly Acids Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2021, Volume: 13, Number: 1, Pages: 73-80 Pages count : 8 DOI: 10.1134/S2070050421010049 | ||||||
| Tags | cellulose, hydrolysis, glucose, cesium salt of heteropoly acid | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 18-33-01007 |
Abstract:
The paper presents the results of studies of catalytic properties of cesium salts of heteropoly acids Cs4–хHхSiW12O40 (x = 3 and 3.5), Cs3–хHхPMo12O40 and Cs3–хHхPW12O40 (x = 2 and 2.5) for hydrolysis of cellulose to glucose at 180°C under argon atmosphere. Glucose is shown to be the main reaction product. The maximum hourly yield equal to 23% is observed in the presence of Cs3HSiW12O40. It is assumed that the catalyst efficiency is affected by the specific surface area. It is established that both heterogeneous and homogeneous processes occur in the presence of the salts due to leaching of the active component to the solution. The prepared salts are demonstrated to be more effective than systems reported previously in literature.
Cite:
Gromov N.V.
, Medvedeva T.B.
, Taran O.P.
, Timofeeva M.N.
, Parmon V.N.
Hydrolysis of Cellulose in the Presence of Catalysts Based on Cesium Salts of Heteropoly Acids
Catalysis in Industry. 2021. V.13. N1. P.73-80. DOI: 10.1134/S2070050421010049 WOS Scopus РИНЦ OpenAlex
Hydrolysis of Cellulose in the Presence of Catalysts Based on Cesium Salts of Heteropoly Acids
Catalysis in Industry. 2021. V.13. N1. P.73-80. DOI: 10.1134/S2070050421010049 WOS Scopus РИНЦ OpenAlex
Original:
Громов Н.В.
, Медведева Т.Б.
, Таран О.П.
, Тимофеева М.Н.
, Пармон В.Н.
Гидролиз целлюлозы в присутствии катализаторов на основе цезиевых солей гетерополикислот
Катализ в промышленности. 2020. Т.20. №3. С.234-242. DOI: 10.18412/1816-0387-2020-3-234-242RSCI РИНЦ AN OpenAlex
Гидролиз целлюлозы в присутствии катализаторов на основе цезиевых солей гетерополикислот
Катализ в промышленности. 2020. Т.20. №3. С.234-242. DOI: 10.18412/1816-0387-2020-3-234-242RSCI РИНЦ AN OpenAlex
Dates:
| Submitted: | Mar 24, 2020 |
| Accepted: | Apr 15, 2020 |
| Published print: | Jan 1, 2021 |
| Published online: | May 14, 2021 |
Identifiers:
| Web of science: | WOS:000650628800008 |
| Scopus: | 2-s2.0-85105827122 |
| Elibrary: | 46072164 |
| OpenAlex: | W3031764407 |