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Enhancement of 1T-MoS2 Superambient Temperature Stability and Hydrogen Evolution Performance by Intercalating a Phenanthroline Monolayer Full article

Journal ChemNanoMat
ISSN: 2199-692X
Output data Year: 2021, Volume: 7, Number: 4, Pages: 447-456 Pages count : 10 DOI: 10.1002/cnma.202000586
Tags hydrogen evolution reaction; intercalations; layered compounds; molybdenum disulfide; organic-inorganic material
Authors Goloveshkin Alexander S. 1 , Lenenko Natalia D. 1 , Naumkin Alexander V. 1 , Pereyaslavtsev Alexander Yu. 2 , Grigorieva Anastasia V. 3 , Shapovalov Aleksei V. 1 , Talanova Valeria N. 1 , Polezhaev Alexander V. 1 , Zaikovskii Vladimir I. 4,5 , Novikov Valentin V. 1 , Korlyukov Alexander A. 1 , Golub Alexandre S. 1
Affiliations
1 A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences
2 The Federal State Unitary Enterprise Dukhov Automatics Research Institute
3 Faculty of Materials Science and Faculty of Chemistry
4 Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences
5 Novosibirsk State University

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation

Abstract: Metastable modification of MoS2 (1T) is widely recognized as a hopeful non-precious electrocatalyst in hydrogen production. This paper describes an approach to impart a superambient temperature stability to 1T-MoS2 by incorporating it in 2D hybrid architecture with cationic monomolecular phenanthrolinium (PhenH+) hydrate layers. The atomic structure and bonding interactions of the assembled architecture revealed by PXRD, TEM, XPS, Raman and UV-Vis spectroscopy data coupled with DFT calculations and quantum theory of atoms in molecules (QTAIM) analysis suggest that the 1T-MoS2 sheets are involved in strong bonding with the PhenH-H2O layers. This results in a highly stable layered system, which is kept intact in 0.5 M sulfuric acid electrolyte and tolerates superambient temperature heating. As compared with pure 1T-MoS2, the compound with a phenanthroline interlayer provides greater activity and better current-voltage efficiency in electrocatalytic hydrogen evolution after heating treatment owing to stabilization of the 1T phase. The obtained results could be useful for the design of novel electrocatalytic devices exploiting 1T-MoS2 modification. © 2020 Wiley-VCH GmbH
Cite: Goloveshkin A.S. , Lenenko N.D. , Naumkin A.V. , Pereyaslavtsev A.Y. , Grigorieva A.V. , Shapovalov A.V. , Talanova V.N. , Polezhaev A.V. , Zaikovskii V.I. , Novikov V.V. , Korlyukov A.A. , Golub A.S.
Enhancement of 1T-MoS2 Superambient Temperature Stability and Hydrogen Evolution Performance by Intercalating a Phenanthroline Monolayer
ChemNanoMat. 2021. V.7. N4. P.447-456. DOI: 10.1002/cnma.202000586 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Nov 3, 2020
Accepted: Nov 23, 2020
Published online: Nov 25, 2020
Published print: Apr 1, 2021
Identifiers:
Web of science: WOS:000621413000001
Scopus: 2-s2.0-85101563581
Elibrary: 46753577
Chemical Abstracts: 2021:844461
Chemical Abstracts (print): 174:862463
OpenAlex: W3107199774
Citing:
DB Citing
Scopus 15
Web of science 14
Elibrary 13
OpenAlex 12
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