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Effect of the Nature of a Support on the Activity of Catalysts Based on 1% Cs/Me0.1Co2.9O4 (Me=Ni,Mg) in Low-Temperature N2O Decomposition Full article

Journal Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Output data Year: 2021, Volume: 95, Number: 3, Pages: 503-511 Pages count : 9 DOI: 10.1134/S0036024421030134
Tags substituted cobalt spinel, supported catalysts, nitrous oxide decomposition, weakly bound oxygen forms, tail gas purification
Authors Isupova L.A. 1 , Ivanova Yu.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation ГЗ-2021-2023

Abstract: The effect of the support (α-Al2O3, Mg2Al4Si5O18, CeO2, TiO2) on the properties of the catalysts based on Ni, Mg-substituted cobalt spinel is investigated via X-ray diffraction, BET adsorption, and О2 temperature-programmed desorption. Their catalytic activity in the reaction of nitrous oxide decomposition at temperatures of 190–400°C is studied. It is shown that the most active and catalytic poison (O2, H2O)–resistant catalyst is one based on magnesium-substituted cobalt spinel on a corundum support 1% Cs/Mg0.1Co2.9O4/α-Al2O3.
Cite: Isupova L.A. , Ivanova Y.A.
Effect of the Nature of a Support on the Activity of Catalysts Based on 1% Cs/Me0.1Co2.9O4 (Me=Ni,Mg) in Low-Temperature N2O Decomposition
Russian Journal of Physical Chemistry A. 2021. V.95. N3. P.503-511. DOI: 10.1134/S0036024421030134 WOS Scopus РИНЦ AN OpenAlex
Original: Исупова Л.А. , Иванова Ю.А.
Влияние природы носителя на активность катализаторов на основе 1% Cs/Me0.1Co2.9O4 (Me = Ni, Mg) в реакции низкотемпературного разложения N2O
Журнал физической химии. 2021. Т.95. №3. С.405-413. DOI: 10.31857/S0044453721030134 РИНЦ OpenAlex
Dates:
Submitted: Aug 20, 2020
Accepted: Aug 24, 2020
Published print: Mar 1, 2021
Published online: Apr 5, 2021
Identifiers:
Web of science: WOS:000636958400008
Scopus: 2-s2.0-85104013996
Elibrary: 46769267
Chemical Abstracts: 2021:812770
OpenAlex: W3146895803
Citing:
DB Citing
Scopus 2
Web of science 1
Elibrary 2
OpenAlex 1
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