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Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range Full article

Journal Journal of Applied Spectroscopy (English Translation of Zhurnal Prikladnoi Spektroskopii)
ISSN: 0021-9037 , E-ISSN: 1573-8647
Output data Year: 2018, Volume: 85, Number: 3, Pages: 374-380 Pages count : 7 DOI: 10.1007/s10812-018-0660-2
Tags amorphous perfluorinated polymers, terahertz range, absorption and refraction spectra, X-ray diffraction analysis
Authors Kitai M.S. 1 , Volkov W.W. 1 , Zharov A.A. 2 , Zubavichus Ya.V. 3 , Konarev P.V. 1,3 , Nazarov M.M. 3 , Polunin E.V. 2 , Pogodina Yu.E. 2 , Sokolov V.I. 1
Affiliations
1 Federal Research Center "Crystallography and Photonics," Russian Academy of Sciences
2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
3 Research Center "Kurchatov Institute"

Abstract: Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and X-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials.
Cite: Kitai M.S. , Volkov W.W. , Zharov A.A. , Zubavichus Y.V. , Konarev P.V. , Nazarov M.M. , Polunin E.V. , Pogodina Y.E. , Sokolov V.I.
Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range
Journal of Applied Spectroscopy (English Translation of Zhurnal Prikladnoi Spektroskopii). 2018. V.85. N3. P.374-380. DOI: 10.1007/s10812-018-0660-2 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Китай М.С. , Волков В.В. , Жаров А.А. , Зубавичус Я.В. , Конарев П.В. , Назаров М.М. , Полунин Е.В. , Погодина Ю.Е. , Соколов В.И.
Оптические свойства аморфных перфторированных полимеров в терагерцовом диапазоне частот
Журнал прикладной спектроскопии. 2018. Т.85. №3. С.364-371. РИНЦ
Dates:
Submitted: Feb 1, 2018
Published print: Jul 3, 2018
Published online: Jul 31, 2018
Identifiers:
Web of science: WOS:000440590800002
Scopus: 2-s2.0-85051054715
Elibrary: 35714299
Chemical Abstracts: 2018:1419364
Chemical Abstracts (print): 170:437869
OpenAlex: W2887936990
Citing:
DB Citing
Web of science 2
Scopus 2
OpenAlex 3
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