Abstract: Formic acid is a liquid organic hydrogen carrier giving hydrogen on demand using catalysts. Metal complexes are known to be used as efficient catalysts for the hydrogen production from formic acid decomposition. Their performance could be better than those of supported catalysts with metal nanoparticles. However, difficulties to separate metal complexes from the reaction mixture limit their industrial applications. This problem can be resolved by supporting metal complexes on the surface of different supports, which may additionally provide some surface sites for the formic acid activation. The review analyzes the literature on the application of supported metal complexes in the hydrogen production from formic acid. It shows that the catalytic activity of some stable Ru and Ir supported metal complexes may exceed the activity of homogeneous metal complexes used for deposition. Non-noble metal-based complexes containing Fe demonstrated sufficiently high performance in the reaction; however, they can be poisoned by water present in formic acid. The proposed review could be useful for development of novel catalysts for the hydrogen production.

Cite: Bulushev D.A.
Progress in Catalytic Hydrogen Production from Formic Acid over Supported Metal Complexes
Energies. 2021. V.14. N5. 1334 :1-14. DOI: 10.3390/en14051334 WOS Scopus РИНЦ AN OpenAlex

Files: Full text from publisher

Dates:

Submitted:	Jan 23, 2021
Accepted:	Feb 22, 2021
Published print:	Mar 1, 2021
Published online:	Mar 1, 2021

Identifiers:

Web of science:	WOS:000628134100001
Scopus:	2-s2.0-85106206675
Elibrary:	46074944
Chemical Abstracts:	2021:1177344
OpenAlex:	W3134468040

Citing:

DB	Citing
Web of science	31
Scopus	34
Elibrary	22
OpenAlex	35

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