Synthesis, X-ray Structure and Biological Activity of Mono- and Dinuclear Copper Complexes Derived from N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methyl-benzenesulfonamide | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis, X-ray Structure and Biological Activity of Mono- and Dinuclear Copper Complexes Derived from N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methyl-benzenesulfonamide Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2021, Volume: 523, Article number : 120408, Pages count : 11 DOI: 10.1016/j.ica.2021.120408

Tags

Azomethines; Copper(II) complex; X-ray absorption spectroscopy; X-ray diffraction; Biological activity

Authors

Vlasenko Valery G. ¹ , Burlov Anatolii S. ² , Koshchienko Yurii V. ² , Kolodina Alexandra A. ² , Chaltsev Bogdan V. ² , Zubavichus Yan V. ³ , Khrustalev Victor N. ^4,5 , Danilenko Tatyana N. ⁶ , Zubenko Alexander A. ⁷ , Fetisov Leonid N. ⁷ , Klimenko Alexander I. ⁷

Affiliations

1	Southern Federal University, Institute of Physics
2	Southern Federal University, Institute of Physical and Organic Chemistry
3	Boreskov Institute of Catalysis SB RAS
4	People's Friendship University of Russia (RUDN University)
5	N. D. Zelinsky Institute of Organic Chemistry RAS
6	Don State Technical University
7	North-Caucasian Zonal Scientific Research Veterinary Institute – Branch of the Federal State Budget Scientific Institution “Federal Rostov Agricultural Research Centre”

Funding (3)

1	Ministry of Science and Higher Education of the Russian Federation	ИнГр/2020-01-ИФ
2	Ministry of Science and Higher Education of the Russian Federation	0239-2021-0002
3	The Ministry of Education and Science of the Russian Federation

A series of copper(II) complexes with new Schiff bases, namely N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methylbenzenesulfonamide [alkyl = ethyl (HL1) or propyl (HL2)], were synthesized using copper acetate or chloride and characterized by elemental analysis, IR and X-ray absorption spectroscopy, and single-crystal X-ray diffraction. The coordination geometry around the Cu(II) ion in Cu(L1)2 and Cu(L2)2 was studied by X-ray absorption spectroscopy. The crystal structures of copper(II) complexes with L1 ligand synthesized from copper chloride and copper acetate with addition of sodium azide have been determined by X-ray diffraction. The azomethines and all copper(II) complexes have been screened for their antibacterial, protistocidal, and fungistatic activities against Penicillium italicum, Colpoda steinii, Escherichia coli 078, and Staphylococcus aureus P-209.

Vlasenko V.G. , Burlov A.S. , Koshchienko Y.V. , Kolodina A.A. , Chaltsev B.V. , Zubavichus Y.V. , Khrustalev V.N. , Danilenko T.N. , Zubenko A.A. , Fetisov L.N. , Klimenko A.I.
Synthesis, X-ray Structure and Biological Activity of Mono- and Dinuclear Copper Complexes Derived from N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methyl-benzenesulfonamide
Inorganica Chimica Acta. 2021. V.523. 120408 :1-11. DOI: 10.1016/j.ica.2021.120408 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Feb 25, 2021
Accepted:	Apr 10, 2021
Published online:	Apr 14, 2021
Published print:	Aug 1, 2021

Web of science:	WOS:000652819800006
Scopus:	2-s2.0-85104641314
Elibrary:	46057184
Chemical Abstracts:	2021:956559
Chemical Abstracts (print):	174:960401
OpenAlex:	W3154224440

DB	Citing
Scopus	9
Web of science	8
Elibrary	11
OpenAlex	9