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Synthesis, X-ray Structure and Biological Activity of Mono- and Dinuclear Copper Complexes Derived from N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methyl-benzenesulfonamide Full article

Journal Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255
Output data Year: 2021, Volume: 523, Article number : 120408, Pages count : 11 DOI: 10.1016/j.ica.2021.120408
Tags Azomethines; Copper(II) complex; X-ray absorption spectroscopy; X-ray diffraction; Biological activity
Authors Vlasenko Valery G. 1 , Burlov Anatolii S. 2 , Koshchienko Yurii V. 2 , Kolodina Alexandra A. 2 , Chaltsev Bogdan V. 2 , Zubavichus Yan V. 3 , Khrustalev Victor N. 4,5 , Danilenko Tatyana N. 6 , Zubenko Alexander A. 7 , Fetisov Leonid N. 7 , Klimenko Alexander I. 7
Affiliations
1 Southern Federal University, Institute of Physics
2 Southern Federal University, Institute of Physical and Organic Chemistry
3 Boreskov Institute of Catalysis SB RAS
4 People's Friendship University of Russia (RUDN University)
5 N. D. Zelinsky Institute of Organic Chemistry RAS
6 Don State Technical University
7 North-Caucasian Zonal Scientific Research Veterinary Institute – Branch of the Federal State Budget Scientific Institution “Federal Rostov Agricultural Research Centre”

Funding (3)

1 Ministry of Science and Higher Education of the Russian Federation ИнГр/2020-01-ИФ
2 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0002
3 The Ministry of Education and Science of the Russian Federation

Abstract: A series of copper(II) complexes with new Schiff bases, namely N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methylbenzenesulfonamide [alkyl = ethyl (HL1) or propyl (HL2)], were synthesized using copper acetate or chloride and characterized by elemental analysis, IR and X-ray absorption spectroscopy, and single-crystal X-ray diffraction. The coordination geometry around the Cu(II) ion in Cu(L1)2 and Cu(L2)2 was studied by X-ray absorption spectroscopy. The crystal structures of copper(II) complexes with L1 ligand synthesized from copper chloride and copper acetate with addition of sodium azide have been determined by X-ray diffraction. The azomethines and all copper(II) complexes have been screened for their antibacterial, protistocidal, and fungistatic activities against Penicillium italicum, Colpoda steinii, Escherichia coli 078, and Staphylococcus aureus P-209.
Cite: Vlasenko V.G. , Burlov A.S. , Koshchienko Y.V. , Kolodina A.A. , Chaltsev B.V. , Zubavichus Y.V. , Khrustalev V.N. , Danilenko T.N. , Zubenko A.A. , Fetisov L.N. , Klimenko A.I.
Synthesis, X-ray Structure and Biological Activity of Mono- and Dinuclear Copper Complexes Derived from N-{2-[(2-diethylamino(alkyl)imino)-methyl]-phenyl}-4-methyl-benzenesulfonamide
Inorganica Chimica Acta. 2021. V.523. 120408 :1-11. DOI: 10.1016/j.ica.2021.120408 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Feb 25, 2021
Accepted: Apr 10, 2021
Published online: Apr 14, 2021
Published print: Aug 1, 2021
Identifiers:
Web of science: WOS:000652819800006
Scopus: 2-s2.0-85104641314
Elibrary: 46057184
Chemical Abstracts: 2021:956559
Chemical Abstracts (print): 174:960401
OpenAlex: W3154224440
Citing:
DB Citing
Scopus 9
Web of science 8
Elibrary 11
OpenAlex 9
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