Nitrogen-Doped Carbon Nanotubes as an Effective Support of Heterogeneous Catalysts for Selective Alkene Oxidation Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2021, Volume: 62, Number: 2, Pages: 288-298 Pages count : 11 DOI: 10.1134/S0023158421020105 | ||
| Tags | carbon nanotubes, nitrogen doping, polyoxometallates, alkenes, liquid-phase oxidation | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0003 |
| 2 | Russian Foundation for Basic Research | 18-33-00764 |
Abstract:
Nitrogen-doped carbon nanotubes (N-CNTs) with different degrees of nitrogen doping were synthesized. The effects of nitrogen in the N-CNTs on the hydrophilic–hydrophobic properties of carbon nanotubes and their activity in the decomposition of Н2О2 were studied. Various approaches to the surface modification of N-CNTs by alkyl groups were studied, and the high resistance of N-CNTs to alkylation was found. Heterogeneous catalysts based on the polyoxometallate [PO4{WO(O2)2}4]3– and N-CNTs with a low degree of nitrogen doping (≤1.8 at %) were successfully synthesized. The high efficiency of the catalysts in the liquid-phase reactions of selective oxidation of alkenes using H2O2 as a green oxidizer was found, and the heterogeneous nature of catalysis was confirmed.
Cite:
Suboch A.N.
, Evtushok V.Y.
, Kibis L.S.
, Kholdeeva O.A.
, Podyacheva O.Y.
Nitrogen-Doped Carbon Nanotubes as an Effective Support of Heterogeneous Catalysts for Selective Alkene Oxidation
Kinetics and Catalysis. 2021. V.62. N2. P.288-298. DOI: 10.1134/S0023158421020105 WOS Scopus РИНЦ AN OpenAlex
Nitrogen-Doped Carbon Nanotubes as an Effective Support of Heterogeneous Catalysts for Selective Alkene Oxidation
Kinetics and Catalysis. 2021. V.62. N2. P.288-298. DOI: 10.1134/S0023158421020105 WOS Scopus РИНЦ AN OpenAlex
Original:
Субоч А.Н.
, Евтушок В.Ю.
, Кибис Л.С.
, Холдеева О.А.
, Подъячева О.Ю.
Углеродные нанотрубки, допированные азотом, как эффективные носители гетерогенных катализаторов селективного окисления алкенов
Кинетика и катализ. 2021. Т.62. №2. С.233-244. DOI: 10.31857/S0453881121020106 РИНЦ OpenAlex
Углеродные нанотрубки, допированные азотом, как эффективные носители гетерогенных катализаторов селективного окисления алкенов
Кинетика и катализ. 2021. Т.62. №2. С.233-244. DOI: 10.31857/S0453881121020106 РИНЦ OpenAlex
Dates:
| Submitted: | Jun 15, 2020 |
| Accepted: | Oct 29, 2020 |
| Published print: | Mar 1, 2021 |
| Published online: | Apr 16, 2021 |
Identifiers:
| Web of science: | WOS:000640512300008 |
| Scopus: | 2-s2.0-85104552544 |
| Elibrary: | 46053843 |
| Chemical Abstracts: | 2021:899262 |
| OpenAlex: | W3153125210 |