New Catalytic Systems with Chemically Fixed Nickel Complexes in the Reactions of Reductive Activation of C-F Bonds in Ionic Liquid Media Full article
| Journal |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Output data | Year: 2021, Volume: 950, Article number : 121995, Pages count : 6 DOI: 10.1016/j.jorganchem.2021.121995 | ||
| Tags | Hydrodefluorination, Hexafluorobenzene, Ionic liquid, Zinc, Nickel complexes, Bipyridine, Covalently bound ligands | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
Abstract:
The nickel complexes with bidentate nitrogen-containing ligands covalently bound to alkylimidazolium cations were obtained for the first time. By the example of the reaction of selective hydrodefluorination of hexafluorobenzene to pentafluorobenzene, it was shown that the catalytic systems ionic liquid - water - covalently bound nickel complex based on the obtained compounds are much more efficient with repeated use in comparison with unfixed nickel complexes. The decisive influence of the cationic fragment of the ionic liquid on the possibility of multiple use of nickel complexes has been established.
Cite:
Prikhod’ko S.A.
, Shabalin A.Y.
, Adonin N.Y.
New Catalytic Systems with Chemically Fixed Nickel Complexes in the Reactions of Reductive Activation of C-F Bonds in Ionic Liquid Media
Journal of Organometallic Chemistry. 2021. V.950. 121995 :1-6. DOI: 10.1016/j.jorganchem.2021.121995 WOS Scopus РИНЦ AN OpenAlex
New Catalytic Systems with Chemically Fixed Nickel Complexes in the Reactions of Reductive Activation of C-F Bonds in Ionic Liquid Media
Journal of Organometallic Chemistry. 2021. V.950. 121995 :1-6. DOI: 10.1016/j.jorganchem.2021.121995 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Mar 31, 2021 |
| Accepted: | Jul 17, 2021 |
| Published online: | Jul 22, 2021 |
| Published print: | Oct 1, 2021 |
Identifiers:
| Web of science: | WOS:000691540300006 |
| Scopus: | 2-s2.0-85111341979 |
| Elibrary: | 46981230 |
| Chemical Abstracts: | 2021:1786995 |
| OpenAlex: | W3186079874 |