Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles | Sciact - CRIS-system of Boreskov Institute of Catalysis

Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2021, Volume: 95, Number: 8, Pages: 1663–1670 Pages count : 8 DOI: 10.1134/S0036024421080318

Tags

thermal decomposition, ortho-phthalates, nanoparticles, copper, nickel, solid solutions, metal/polymer composites, quantum size effect

Authors

Yudanova L.I. ¹ , Ishchenko A.V. ² , Rudina N.A. ²

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090 Russia

A comparison is made of the thermoanalytical characteristics and the composition and structure of solid products of the thermal decomposition of ortho-phthalates [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)](H2O)2. It is found that the thermal decomposition of these compounds upon heating to 500°C in a He atmosphere can be conditionally divided into two stages: dehydration and decarboxylation. Polymer conglomerates containing uncoated Cu nanoparticles as large as 75 nm are embedded into the polymer matrix of the composite obtained via the thermal decomposition of [Cu(H2O)2(C8H4O4)]. Three types of nanoparticles with sizes of 40–85, 15–25, and 10–15 nm are embedded in the polymer matrices of composites. The particles are Cux/Ni1−x solid solutions of different compositions, obtained via the thermolysis of [CuNi(H2O)4(C8H4O4)2]. It is found that the onset temperature of [CuNi(H2O)4(C8H4O4)2] decarboxylation at the third part of the second stage with the formation of a three-phase region correlates with the temperature of decomposition of Cux/Ni1 – x solid solutions in the binary metal system, due apparently to the quantum size effect.

Yudanova L.I. , Ishchenko A.V. , Rudina N.A.
Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles
Russian Journal of Physical Chemistry A. 2021. V.95. N8. P.1663–1670. DOI: 10.1134/S0036024421080318 WOS Scopus РИНЦ AN OpenAlex

Юданова Л.И. , Ищенко А.В. , Рудина Н.А.
Термическое разложение [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2] и [Ni(H2O)2(C8H4O4)2](H2O)2 с образованием металлических и биметаллических наночастиц
Журнал физической химии. 2021. Т.95. №8. С.1241-1248. DOI: 10.31857/s0044453721080318 РИНЦ OpenAlex

Submitted:	Oct 15, 2020
Accepted:	Nov 3, 2020
Published print:	Aug 1, 2021
Published online:	Aug 22, 2021

Web of science:	WOS:000687169000022
Scopus:	2-s2.0-85113229745
Elibrary:	47011389
Chemical Abstracts:	2021:1848902
OpenAlex:	W3195352694

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