Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions Научная публикация
| Журнал |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Вых. Данные | Год: 2021, Том: 152, Страницы: 2025–2032 Страниц : 8 DOI: 10.1007/s10562-021-03798-z | ||
| Ключевые слова | N-phosphonomethyl iminodiacetic acid N-oxide · Metal complex catalysis · Phase transfer catalysis · Catalytic oxidation · Hydrogen peroxide | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0005 |
Реферат:
Oxidation of the N–phosphonomethyl iminodiacetic acid (PMIDA) with hydrogen peroxide in a two-phase system (aqueous phase—organic phase) in the presence of the [(Octn)3NMe]3{PO4[WO(O2)2]4} catalyst was studied and the kinetic parameters of this reaction were determined. It was found that the PMIDA oxidation with aqueous H2O2 proceeds only in the presence of the catalyst giving PMIDA N-oxide as the main product. Under the studied conditions, the reaction orders with respect to the reagents (PMIDA and H2O2) and the catalyst were found to be the first. The apparent activation energy of the reaction for the temperature range of 313–343 K is 37 ± 3 kJ/mol.
Библиографическая ссылка:
Yushchenko D.Y.
, Pai Z.P.
, Khlebnikova T.B.
Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions
Catalysis Letters. 2021. V.152. P.2025–2032. DOI: 10.1007/s10562-021-03798-z WOS Scopus РИНЦ CAPlus OpenAlex
Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions
Catalysis Letters. 2021. V.152. P.2025–2032. DOI: 10.1007/s10562-021-03798-z WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 7 июн. 2021 г. |
| Принята к публикации: | 9 сент. 2021 г. |
| Опубликована online: | 18 сент. 2021 г. |
| Опубликована в печати: | 1 июл. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000697086500002 |
| Scopus: | 2-s2.0-85115169578 |
| РИНЦ: | 47045876 |
| Chemical Abstracts: | 2021:2062080 |
| OpenAlex: | W3200721457 |