Homogeneous Redox Catalysts Based on Heteropoly Acid Solutions: IV. Tests of Methyl Ethyl Ketone Synthesis Catalysts in the Presence of Equipment Corrosion Products (Metal Cations) Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2021, Volume: 62, Number: 5, Pages: 580-591 Pages count : 12 DOI: 10.1134/S002315842105013X | ||
| Tags | heteropoly acids; homogeneous catalysis; butylene oxidation; methyl ethyl ketone | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
Abstract:
The effect of equipment corrosion products (transition metal cations) on the physicochemical and catalytic properties of a homogeneous Pd(II)+HPA-x (Mo-V-P heteropoly acid containing x vanadium atoms) catalyst developed for the two-stage oxidation of n-butene to methyl ethyl ketone (MEK) with oxygen has been studied. The thermal stability of a solution of a catalyst based on HPA-x in the presence of transition metal cations has been determined. The composition of the two-component catalyst recommended for pilot testing of the MEK process has been optimized.
Cite:
Zhizhina E.G.
, Gogin L.L.
Homogeneous Redox Catalysts Based on Heteropoly Acid Solutions: IV. Tests of Methyl Ethyl Ketone Synthesis Catalysts in the Presence of Equipment Corrosion Products (Metal Cations)
Kinetics and Catalysis. 2021. V.62. N5. P.580-591. DOI: 10.1134/S002315842105013X WOS Scopus РИНЦ AN OpenAlex
Homogeneous Redox Catalysts Based on Heteropoly Acid Solutions: IV. Tests of Methyl Ethyl Ketone Synthesis Catalysts in the Presence of Equipment Corrosion Products (Metal Cations)
Kinetics and Catalysis. 2021. V.62. N5. P.580-591. DOI: 10.1134/S002315842105013X WOS Scopus РИНЦ AN OpenAlex
Original:
Жижина Е.Г.
, Гогин Л.Л.
Гомогенные катализаторы окислительно-восстановительных процессов на основе растворов гетерополикислот. IV. Испытания катализатора синтеза метилэтилкетона в присутствии продуктов коррозии аппаратуры (катионов металлов)
Кинетика и катализ. 2021. Т.62. №5. С.536-548. DOI: 10.31857/S0453881121050142 РИНЦ OpenAlex
Гомогенные катализаторы окислительно-восстановительных процессов на основе растворов гетерополикислот. IV. Испытания катализатора синтеза метилэтилкетона в присутствии продуктов коррозии аппаратуры (катионов металлов)
Кинетика и катализ. 2021. Т.62. №5. С.536-548. DOI: 10.31857/S0453881121050142 РИНЦ OpenAlex
Dates:
| Submitted: | Mar 12, 2021 |
| Accepted: | May 19, 2021 |
| Published print: | Sep 1, 2021 |
| Published online: | Sep 25, 2021 |
Identifiers:
| Web of science: | WOS:000699025100004 |
| Scopus: | 2-s2.0-85115680211 |
| Elibrary: | 47076433 |
| Chemical Abstracts: | 2021:2110650 |
| OpenAlex: | W3204503758 |