Effects of Components Interaction in the MoO3/Al2O3 Catalysts on Their Catalytic Properties in Propylene Metathesis Научная публикация
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Техника и технология нефтехимического и нефтегазового производства : 11-я Международная научно-техническая конференция 24-27 февр. 2021 , Омск |
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| Сборник | Oil and Gas Engineering, OGE 2021. - Сер. Oil and Gas Engineering, OGE 2021 Сборник, AIP Conference Proceedings. 2021. 831 c. ISBN 9780735441682. РИНЦ |
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| Вых. Данные | Год: 2021, Том: 2412, Номер статьи : 020006, Страниц : 7 DOI: 10.1063/5.0075181 | ||
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0006 |
Реферат:
ABSTRACT
A series of MoO3/Al2O3 catalysts with a molybdenum oxide loading from 2 till 10 wt.% was prepared by incipient wetness impregnation of the support with a solution of molybdenum citrate complex. The use of citric acid in the impregnation solution during the preparation of MoO3/Al2O3 catalysts favoured the formation of highly dispersed molybdenum species. The degree of aggregation of molybdenum species in catalysts depended both on the molybdenum oxide loading and on the activation conditions. Samples containing mainly tetrahedrally coordinated molybdenum species in the form of surface monomolybdates according to UV-DRS data were active in the propylene metathesis. The catalyst loaded 7 wt.% MoO3 was the most active in the propylene metathesis reaction. It exhibited propylene conversion of 30% and a metathesis product selectivity of 96% at a temperature of 200 °C.
Библиографическая ссылка:
Karpova T.R.
, Moiseenko M.A.
, Buluchevskiy E.A.
, Arbuzov A.B.
, Lavrenov A.V.
Effects of Components Interaction in the MoO3/Al2O3 Catalysts on Their Catalytic Properties in Propylene Metathesis
В сборнике Oil and Gas Engineering, OGE 2021. - Сер. Oil and Gas Engineering, OGE 2021. – AIP Conference Proceedings., 2021. – Т.2412. – ISBN 9780735441682. DOI: 10.1063/5.0075181 Scopus РИНЦ CAPlus OpenAlex
Effects of Components Interaction in the MoO3/Al2O3 Catalysts on Their Catalytic Properties in Propylene Metathesis
В сборнике Oil and Gas Engineering, OGE 2021. - Сер. Oil and Gas Engineering, OGE 2021. – AIP Conference Proceedings., 2021. – Т.2412. – ISBN 9780735441682. DOI: 10.1063/5.0075181 Scopus РИНЦ CAPlus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-85122326573 |
| РИНЦ: | 47902664 |
| Chemical Abstracts: | 2022:824842 |
| OpenAlex: | W4205679531 |
Цитирование в БД:
| БД | Цитирований |
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| Scopus | 1 |