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Detecting Spatial Inhomogeneity Manifestations in the Chemical Composition of Functional Materials by Stoichiographic Methods Обзор

Журнал Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Вых. Данные Год: 2014, Том: 55, Номер: 6, Страницы: 1160-1165 Страниц : 6 DOI: 10.1134/S0022476614060262
Ключевые слова Differential dissolution method, Inhomogeneity of the composition and structure of solid, Mathematical simulation of dynamic dissolution, Phase analysis
Авторы Pochtarʹ A.A. 1,2 , Vasilʹeva I.G. 3 , Malakhov V.V. 1,2
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2 Novosibirsk State University, Novosibirsk, Russia
3 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 11-03-00093
2 Президиум РАН 8

Реферат: A review is made of the physicochemical factors causing the variability of the properties of inorganic solid phases having the same stoichiometry of the elemental composition, but different actual structures. These factors lead to spatial inhomogeneity in the composition and structure of the solid phases and determine the time profile of the stoichiograms and kinetic dependences for the dissolution of these substances in the dynamic differential dissolution (DD) mode. A discussion is given of the results obtained by mathematical simulation of dynamic dissolution of solid phase mixtures, which show how the selectivity and efficiency of the separation of the phase mixtures depends on their dispersion ability. Various aspects are considered of the use of the DD method for detecting spatial inhomogeneity manifestations in the composition and structure of solids and materials.
Библиографическая ссылка: Pochtarʹ A.A. , Vasilʹeva I.G. , Malakhov V.V.
Detecting Spatial Inhomogeneity Manifestations in the Chemical Composition of Functional Materials by Stoichiographic Methods
Journal of Structural Chemistry. 2014. V.55. N6. P.1160-1165. DOI: 10.1134/S0022476614060262 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная: Почтарь А.А. , Васильева И.Г. , Малахов В.В.
Определение проявлений пространственной неоднородности химического состава функциональных материалов методами стехиографии
Журнал структурной химии. 2014. Т.55. №6. С.1216-1221. RSCIRSCI РИНЦ
Даты:
Поступила в редакцию: 28 апр. 2014 г.
Опубликована в печати: 1 нояб. 2014 г.
Опубликована online: 24 янв. 2015 г.
Идентификаторы БД:
Web of science: WOS:000348401200026
Scopus: 2-s2.0-84921724607
РИНЦ: 24030429
Chemical Abstracts: 2015:145428
OpenAlex: W2057048706
Цитирование в БД:
БД Цитирований
Web of science 2
Scopus 2
РИНЦ 3
OpenAlex 2
Альметрики: